Journal of Physical Chemistry B, Vol.103, No.19, 3900-3907, 1999
Kinetics and mechanism of gold dendrite electroformation on C(0001). Activation energy for gold adatom surface diffusion
Au electrodeposition on C(0001) from aqueous solutions with different concentrations of AuCl3. HCl, at a constant ionic mass transport rate (j(L)) in the temperature range 275 less than or equal to T less than or equal to 313 K, results in the initial formation of nanometer-sized Au islands consisting of a central core and symmetrically distributed branches with the island fractal dimension D-t = 1.6. For all values of T, the time dependence of the Au island radius fulfills a r proportional to t(n) relationship with n = 0.25 +/- 0.05. At constant T, the density of Au islands (N-s) increases according to N-s proportional to j(L)(X) with X = 0.69 +/- 0.03. At constant j(L), the value of N-s decreases as T is increased, following an Arrhenius-type relationship. Kinetic data are consistent with a growth mechanism involving surface diffusion of Au adatoms from the island core towards branch tips. From the dependence of N-s on T at constant j(L), the activation energy for Au adatom surface diffusion results in E-a* approximate to 11 Kcal/mol. This figure is slightly smaller than E-a* approximate to 14 Kcal/mol that has been reported for Au atom surface diffusion in Cl--ion free acid solutions.