A network simulation method, based on the theory of network thermodynamics, is applied in this work to the description of the structure of the double layer around a spherical colloidal particle, in the presence of an externally applied constant electric field. It is demonstrated that the system of differential equations governing the phenomena involved is formally equivalent to that of:a properly designed electric circuit, obtained as a series of subcircuits corresponding to each of the volume elements into which the system is divided. A simulation program is then used to solve the circuit in order to obtain the quantities of interest. The methodology is first applied to the calculation of the electrophoretic mobility of a spherical colloidal particle, and of the de conductivity of a dilute suspension of spheres. The results are compared to the predictions of O＇ Brien and White＇s classical theories, and an excellent agreement is found in all cases checked. We emphasize that the network technique not only avoids the knowledge of sophisticated numerical integration methods but also allows one to readily obtain the profiles of any physical variable of interest (potential, ionic concentrations, fluid velocity, for instance) at all points of the double layer. The polarization of the latter under the action of the applied external field is easily described in terms of the dependence of the variables with the distance to the particle＇s surface. The power of the method is illustrated by the calculation of ion concentrations, and potential and velocity profiles in the presence of the external electric field.