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Polymer Engineering and Science, Vol.58, No.3, 438-446, 2018
Mathematical modeling and analysis of an interfacial polycarbonate polymerization in a continuous multizone tubular reactor
A detailed mathematical model is presented to describe the steady state behavior of a continuous multizone tubular reactor for the synthesis of aromatic polycarbonate by interfacial polycondensation mechanism. In this process, bisphenol-A dissolved in a dispersed aqueous phase reacts with phosgene dissolved in a continuous organic phase and hence, the reaction initiates at the interface of the two phases. A liquid-liquid mass transfer process is incorporated into a reaction kinetic model to calculate the reaction rates and polymer molecular weight distribution. The kinetic model has also been used in developing a steady state multizone tubular reactor model for continuous production of polycarbonate. The model simulations are compared with proprietary plant data and excellent agreement has been obtained. POLYM. ENG. SCI., 58:438-446, 2018. (c) 2017 Society of Plastics Engineers