화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.62, 46-51, June, 2018
Robust anti-icing performance of silicon wafer with hollow micro-/nano-structured ZnO
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A novel silicon-based robust anti-icing surface with hollow micro-/nano-structured ZnO (HMN) is investigated. The droplet could not freeze in 30 min under low temperature of -15 °C, while that performance fails on the nano-structured and smooth surfaces. The cooling period of temperature fields on liquid droplet and the base are observed, which indicates that the air layer has a significant effect on the performance of the anti-icing surface. The results prove that the hollow micro-structure layer provides much more air than the nano-structured layer and induces the maximum thermal resistance, leading to its icephobic property. In this finding, HMN provides large thermal resistance between the base and liquid droplet and easily realizes long lasting anti-icing performance under lower temperature. This new concept is expected to be used in the fields of anti-icing, superhydrophobicity, insulation, thermal resistance, etc.
  1. Wang J, Han F, Liang B, Geng G, J. Ind. Eng. Chem., 54, 174 (2017)
  2. Wang L, Gong QH, Zhan SH, Jiang L, Zheng YM, Adv. Mater., 28(35), 7729 (2016)
  3. Kang Z, Li W, J. Ind. Eng. Chem., 50, 50 (2017)
  4. Boreyko J, Chen CH, Phys. Rev. Lett., 103, 184501 (2009)
  5. Chu F, Wu X, Zhu B, Zhang X, Appl. Phys. Lett., 108, 194103 (2016)
  6. Liu M, Wang S, Jiang L, Nat. Rev. Mater., 2(7), 17036 (2017)
  7. Golovin K, Kobaku SP, Lee DH, DiLoreto ET, Mabry JM, Tuteja A, Sci. Adv., 2, e15014 (2016)
  8. Yang C, Yang X, Li F, Li T, Cao W, J. Ind. Eng. Chem., 39, 93 (2016)
  9. Zhang Q, He M, Chen J, Wang J, Song Y, Jiang L, Chem. Commun., 49, 4516 (2013)
  10. Nagappan S, Lee DB, Seo DJ, Park SS, Ha CS, J. Ind. Eng. Chem., 22, 288 (2015)
  11. Boreyko J, Collier CP, ACS Nano, 7(2), 1618 (2013)
  12. Lv J, Song Y, Jiang L, Wang J, ACS Nano, 8(4), 3152 (2014)
  13. Wen M, Wang L, Zhang M, Jiang L, Zheng Y, ACS Appl. Mater. Interfaces, 6, 3963 (2014)
  14. Chen Y, Liu G, Jiang L, Kim JY, Ye F, Lee JK, Wang L, Wang B, Chin. Phys. B, 26, 046801 (2017)
  15. Zhong H, Lukes JR, Phys. Rev. B, 74, 125403 (2006)
  16. Liu G, Peng M, Song W, Wang H, Zou D, Nano Energy, 11, 341 (2015)
  17. Liu G, Gao X, Wang H, Kim AY, Zhao Z, Lee JK, Zou D, J. Mater. Chem. A, 4, 5925 (2016)
  18. Li W, Sha X, Dong W, Wang Z, Chem. Commun., 20, 2434 (2002)
  19. Zhao Z, Liu G, Li B, Guo L, Fei C, Wang Y, Lv L, Liu X, Tian J, Cao G, J. Mater. Chem. A, 3, 11320 (2015)
  20. Koo HJ, Kim YJ, Lee YH, Lee WI, Kim K, Park NG, Adv. Mater., 20(1), 195 (2008)
  21. Liu J, Dai M, Wang T, Sun P, Liang X, Lu G, Shimanoe K, Yamazoe N, ACS Appl. Mater. Interfaces, 8, 6669 (2016)
  22. Zhang J, Cao Y, Wang CA , Ran R, ACS Appl. Mater. Interfaces, 8, 8670 (2016)
  23. Zhu Y, Lei J, Tian Y, Dalton Trans., 43, 7275 (2014)
  24. Liu J, Luo T, Meng F, Sun B, Li M, Liu J, Chem. Commun., 46, 472 (2010)
  25. Wang L, Wen M, Zhang M, Jiang L, Zheng Y, J. Mater. Chem. A, 2, 3312 (2014)
  26. Schutzius TM, Jung S, Maitra T, Graeber G, Kohme M, Poulikakos D, Nature, 527(7576), 82 (2015)
  27. Fu SP, Sahu RP, Diaz E, Robles JR, Chen C, Rui X, Kile RF, Yarin AL, Abiade JT, Langmuir, 32(24), 6148 (2016)
  28. Hao C, Liu Y, Chen X, Li J, Zhang M, Zhao Y, Wang Z, Small, 12, 1825 (2016)
  29. Wang L, Shi W, Hou Y, Zhang M, Feng S, Zheng Y, Adv. Mater. Interfaces, 2, 150004 (2015)
  30. Kreder MJ, Alvarenga J, Kim P, Aizenberg J, Nat. Rev. Mater., 1, 15003 (2016)
  31. Tian Y, Su B, Jiang L, Adv. Mater., 26(40), 6872 (2014)
  32. Ruan M, Li W, Wang BS, Deng BW, Ma FM, Yu ZL, Langmuir, 29(27), 8482 (2013)
  33. Chu F, Wu X, Wang L, ACS Appl. Mater. Interfaces, 9, 8420 (2017)
  34. Li D, Wu Y, Kim P, Shi L, Yang P, Majumdar A, Appl. Phys. Lett., 83, 2934 (2003)
  35. Valle VHD, Kenning DBR, Int. J. Heat Mass Transf., 28, 1907 (1985)
  36. Sun KH, Lienhard JH, Int. J. Heat Mass Transf., 13, 1425 (1970)