Sulfur-doped nickel oxide spherical nanosheets for redox supercapacitors

Bal Sydulu Singu; Sang Eun Hong; Kuk Ro Yoon

Journal of Industrial and Engineering Chemistry, Vol.62, 321-328, June, 2018

DOI10.1016/j.jiec.2018.01.010 Export Citation

Sulfur-doped nickel oxide spherical nanosheets for redox supercapacitors

Bal Sydulu Singu, Sang Eun Hong, and Kuk Ro Yoon^†

Organic Nanomaterials Lab, Department of Chemistry, Hannam University, Daejeon 305-811, Republic of Korea

E-mail:

We have synthesized sulfur-doped nickel oxide (S-NiO) spherical nanosheets by emulsion method. The structure of the S-NiO nanosheets is characterized by using TGA, XRD, XPS, BET, FE-SEM and FE-TEM. From the TGA, XPS and EDAX results conclude the nickel oxide is doped with sulfur. The specific capacitance of the S-NiO nanosheets was showing 313 F g-1 at the sweep rate of 5 mV s-1 by cyclic voltammetry. The S-NiO nanosheets showing the high rate performance of 80% at the current density ranging from 1 to 8 A g-1 and high retention of the capacitance 99% after completion of 1000 charge. discharge cycles.

Keywords:Sulfur;Nickel oxide;Doped;Supercapacitor;Nanosheets

[References]

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Singu BS, Male U, Srinivasan P, Yoon KR, J. Ind. Eng. Chem., 49, 82 (2017)
Barai HR, Banerjee AN, Joo SW, J. Ind. Eng. Chem., 56, 212 (2017)
Park HW, Na BK, Cho BW, Park SM, Roh KC, Phys. Chem. Chem. Phys., 15(40), 17626 (2013)
Pawar SA, Patil DS, Shin JC, J. Ind. Eng. Chem., 54, 162 (2017)
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Lang JW, Kong LB, Wu WJ, Luo YC, Chem. Commun., 104(35), 4213 (2008)
Cao X, Shi Y, Shi W, Lu G, Huang X, Yan Q, Zhang Q, Zhang H, Small, 7(22), 3163 (2011)
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Singu BS, Male U, Hong SE, Yoon KR, Ionics, 22(8), 1485 (2016)
Dong L, Chu Y, Sun W, Chem.: Eur. J., 14(16), 5064 (2008)
Patterson JM, Kortylewicz Z, Smith WT, J. Agric. Food Chem., 32(4), 782 (1984)
Singu BS, Yoon KR, J. Ind. Eng. Chem., 33, 374 (2016)
Huang QH, Wang XY, Li J, Dai CL, Gamboa S, Sebastian PJ, J. Power Sources, 164(1), 425 (2007)
Wang DC, Ni WB, Pang H, Lu QY, Huang ZJ, Zhao JW, Electrochim. Acta, 55(22), 6830 (2010)
Han DD, Jing XY, Wang J, Yang PP, Song DL, Liu JY, J. Electroanal. Chem., 682, 37 (2012)
Biesinger MC, Payne BP, Lau LWM, Gerson A, Smart RSC, Surf. Interface Anal., 41(4), 324 (2009)
Guai GH, Leiw MY, Ng CM, Li CM, Adv. Energy Mater., 2(3), 334 (2012)
Dubal DP, Jagadale AD, Patil SV, Lokhande CD, Mater. Res. Bull., 47(5), 1239 (2012)
Singu BS, Yoon KR, Electrochim. Acta, 231, 749 (2017)
Cao F, Pan GX, Xia XH, Tang PS, Chen HF, J. Power Sources, 264, 161 (2014)
Singu BS, Male U, Srinivasan P, Pabba S, J. Solid State Electrochem., 18(7), 1995 (2014)
Singu BS, Srinivasan P, Yoon KR, J. Solid State Electrochem., 20(12), 3447 (2016)

[Referenced By]

[1] Wang H, Wang Y, Wang X, Electrochem. Commun., 18(1), 92 (2012)

[2] Sahoo S, Shim JJ, J. Ind. Eng. Chem., 54, 205 (2017)

[3] Singu BS, Male U, Srinivasan P, Yoon KR, J. Ind. Eng. Chem., 49, 82 (2017)

[4] Barai HR, Banerjee AN, Joo SW, J. Ind. Eng. Chem., 56, 212 (2017)

[5] Park HW, Na BK, Cho BW, Park SM, Roh KC, Phys. Chem. Chem. Phys., 15(40), 17626 (2013)

[6] Pawar SA, Patil DS, Shin JC, J. Ind. Eng. Chem., 54, 162 (2017)

[7] Wei W, Cui X, Chen W, Ivey DG, Chem. Soc. Rev., 40(3), 1697 (2011)

[8] Sun X, Wang G, Hwang JY, Lian J, J. Mater. Chem., 21, 16581 (2011)

[9] Nam KW, Kim KB, J. Electrochem. Soc., 149(3), A346 (2002)

[10] Dhole IA, Navale ST, Navale YH, Jadhav YM, Pawar CS, Suryavanshi SS, Patil VB, J. Mater. Sci. Mater. Electron., 28(15), 10819 (2017)

[11] Kate RS, Khalate SA, Deokate RJ, J. Anal. Appl. Pyrolysis, 125, 289 (2017)

[12] Paulose R, Mohan R, Parihar V, Nano Struct. Nano Objects, 11, 102 (2017)

[13] Kate RS, Khalate SA, Deokate RJ, J. Alloy. Compd., 734, 89 (2018)

[14] Lang JW, Kong LB, Wu WJ, Luo YC, Chem. Commun., 104(35), 4213 (2008)

[15] Cao X, Shi Y, Shi W, Lu G, Huang X, Yan Q, Zhang Q, Zhang H, Small, 7(22), 3163 (2011)

[16] Qiu Y, Yu J, Zhou X, Tan C, Yin J, Nanoscale Res. Lett., 4(2), 173 (2008)

[17] Lu Z, Chang Z, Liu J, Sun X, Nano Res., 4(7), 658 (2011)

[18] Zhang X, Shi W, Zhu J, Zhao W, Ma J, Mhaisalkar S, Maria TL, Yang Y, Zhang H, Hng HH, Yan Q, Nano Res., 3(9), 643 (2010)

[19] Salavati-Niasari M, Mir N, Davar F, J. Alloy. Compd., 493(1-2), 163 (2010)

[20] Ding S, Zhu T, Chen JS, Wang Z, Yuan C, Lou XW, J. Mater. Chem., 21, 6602 (2011)

[21] Yan X, Tong X, Wang J, Gong C, Zhang M, Liang L, Mater. Lett., 95, 1 (2013)

[22] Xu J, Gao L, Cao J, Wang W, Chen Z, J. Solid State Electrochem., 15(9), 2005 (2011)

[23] Paravannoor A, Ranjusha R, Asha AM, Vani R, Kalluri S, Subramanian KRV, Sivakumar N, Kim TN, Nair SV, Balakrishnan A, Chem. Eng. J., 220, 360 (2013)

[24] Ren B, Fan MQ, Liu Q, Wang J, Song DL, Bai XF, Electrochim. Acta, 92, 197 (2013)

[25] Pang H, Zhang B, Du J, Chen J, Zhang J, RSC Adv., 2(6), 2257 (2012)

[26] Liang K, Tang X, Hu W, J. Mater. Chem., 22(22), 11062 (2012)

[27] Wu HY, Wang HW, Int. J. Electrochem. Sci., 7(5), 4405 (2012)

[28] Zhu ZH, Ping J, Huang XP, Hu JG, Chen QY, Ji XB, Banks CE, J. Mater. Sci., 47(1), 503 (2012)

[29] Singu BS, Male U, Hong SE, Yoon KR, Ionics, 22(8), 1485 (2016)

[30] Dong L, Chu Y, Sun W, Chem.: Eur. J., 14(16), 5064 (2008)

[31] Patterson JM, Kortylewicz Z, Smith WT, J. Agric. Food Chem., 32(4), 782 (1984)

[32] Singu BS, Yoon KR, J. Ind. Eng. Chem., 33, 374 (2016)

[33] Huang QH, Wang XY, Li J, Dai CL, Gamboa S, Sebastian PJ, J. Power Sources, 164(1), 425 (2007)

[34] Wang DC, Ni WB, Pang H, Lu QY, Huang ZJ, Zhao JW, Electrochim. Acta, 55(22), 6830 (2010)

[35] Han DD, Jing XY, Wang J, Yang PP, Song DL, Liu JY, J. Electroanal. Chem., 682, 37 (2012)

[36] Biesinger MC, Payne BP, Lau LWM, Gerson A, Smart RSC, Surf. Interface Anal., 41(4), 324 (2009)

[37] Guai GH, Leiw MY, Ng CM, Li CM, Adv. Energy Mater., 2(3), 334 (2012)

[38] Dubal DP, Jagadale AD, Patil SV, Lokhande CD, Mater. Res. Bull., 47(5), 1239 (2012)

[39] Singu BS, Yoon KR, Electrochim. Acta, 231, 749 (2017)

[40] Cao F, Pan GX, Xia XH, Tang PS, Chen HF, J. Power Sources, 264, 161 (2014)

[41] Singu BS, Male U, Srinivasan P, Pabba S, J. Solid State Electrochem., 18(7), 1995 (2014)

[42] Singu BS, Srinivasan P, Yoon KR, J. Solid State Electrochem., 20(12), 3447 (2016)