Organosilicon resin-based carbon/ceramic polygranular composites with improved oxidation resistance

Krystian Sokolowski; Aneta Fraczek-Szczypta; Janusz Tomala; Stanislaw Blazewicz

Korean Journal of Chemical Engineering, Vol.35, No.6, 1354-1364, June, 2018

DOI10.1007/s11814-018-0029-5 Export Citation

Organosilicon resin-based carbon/ceramic polygranular composites with improved oxidation resistance

Krystian Sokolowski, Aneta Fraczek-Szczypta, Janusz Tomala¹, and Stanislaw Blazewicz^†

Department of Biomaterials and Composites, Faculty of Materials Science and Ceramics, AGH, University of Science and Technology, Al. Mickiewicza 30, 30-059 Cracow, Poland
¹SGL Carbon Polska S.A., ul. Piastowska 29, 47-400 Raciborz, Poland

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We examined the thermo-mechanical properties of carbon materials modified with silicon oxycarbide (Si- O-C) and silicon carbide (Si-C). These compounds were obtained by the impregnation of carbon components with a silicon-containing polymer resin. Graphite and anthracite powders were used as carbon components, and poly[methyl(phenyl) siloxane] resin (P) was used as the ceramic precursor. Carbon/polymer compositions (C/P) were subjected to twostage annealing, first to 1,000 °C and next to 2,000 °C in an inert atmosphere, leading to the formation of C/Si-O-C and C/Si-C composite samples, respectively. The materials were then examined under conditions of isothermal oxidation to determine their oxidation resistance and the mechanical properties before and after oxidation tests. The structure of the samples before and after oxidation was studied. C/Si-C composites, despite their high porosity, proved to have enhanced resistance to oxidation at 600 °C, although they had lower mechanical properties in comparison to C/Si-O-C samples.

Keywords:Polysiloxane Resin;Carbon Materials;Silicon Oxycarbide;Silicon Carbide;Oxidation Resistance

[References]

McKee DW, Fundamental Issues in Control of Carbon Gasification Reactivity, 192, 483 (1991).
Manocha LM, Sadhana, 28, 349 (2003)
Sogabe T, Okada O, Kuroda K, Inagaki M, Carbon, 35, 67 (1997)
Fitzer G, Manocha LM, Carbon Reinforcement and Carbon/Carbon Composites, 281 (1998).
Wu X, Radovic LR, Carbon, 44, 141 (2006)
Isola C, Appendino P, Bosco F, Ferraris M, Salvo M, Carbon, 36, 1213 (1998)
Lu W, Chung DDL, Carbon, 40, 1249 (2002)
Walter S, Soraru GD, Brequel H, Enzo S, J. European Ceram. Soc., 22, 2389 (2002)
Semchenko GD, Shuteeva IY, Slepchenko ON, Angolenko LA, Refractories Industrial Ceramics, 46, 260 (2005)
Kowbel W, Withers JC, Ransone PO, Carbon, 33, 415 (1995)
Ho CT, Chung DDL, Carbon, 28, 815 (1990)
Yoo HI, Kim HS, Hong BG, Sihn IC, Lim KH, Lim BJ, Moon SY, J. European Ceram. Soc., 36, 1581 (2016)
Dhami TL, Bahl OP Awasthy BR, Carbon, 33, 479 (1995)
Lespade P, Richet N, Goursat P, Acta Astronaut., 60, 858 (2007)
Zhu YC, Ohtani S, Sato Y, Iwamoto N, Carbon, 36, 929 (1998)
Manocha LM, Manocha S, Patel KB, Glogar P, Carbon, 38, 1481 (2000)
Li HJ, Xue H, Wang YJ, Fu QG, Yao DJ, Surf. Coat. Technol., 201, 9444 (2007)
Paluszkiewicz C, Gumula T, Podporska J, Blazewicz M, J. Mol. Struct., 792, 176 (2006)
Xia K, Lu C, Yang Y, New Carbon Materials, 30, 236 (2015)
Weinmann M, Ionescu E, Riedel R, Aldinger F, Advanced Ceramics, 2, 1025 (2013)
Schiavon MA, Radovanovic E, Yoshida IVP, Powder Technol., 123(2-3), 232 (2002)
Kolar F, Machovic V, Svitilova J, Borecka L, Mater. Chem. Phys., 86(1), 88 (2004)
Kwon OS, Hong SH, Kim H, J. European Ceram. Soc., 23, 3119 (2003)
Schiavon MA, Redondo SUA, Pina SRO, Yoshida IVP, J. Non-Cryst. Solids, 304, 92 (2002)
Duan L, Ma Q, Chen Z, J. European Ceram. Soc., 33, 841 (2013)
Gumula T, Paluszkiewicz C, Blazewicz M, J. Mol. Struct., 704, 259 (2004)
Xu T, Ma Q, Wang Y, Chen Z, Ceram. Int., 40, 13787 (2014)
Li ZQ, Lu CJ, Xia ZP, Zhoh Y, Luo Z, Carbon, 45, 1686 (2007)
Gumula T, Paluszkiewicz C, Blazewicz S, J. Anal. Appl. Pyrolysis, 86, 375 (2009)
Wu Q, Zhang Q, Zhao L, Li SN, Wu LB, Jiang JX, Tang LC, J. Hazard. Mater., 336, 222 (2017)
Guan L, Gao J, Pei Y, Zhao L, Gong L, Wan Y, Zhou Zheng N, Du X, Wu L, Jiang J, Liu H, Tang L, Mai Y, Carbon, 107, 573 (2016)
Yang X, Huang Q, Su Z, Chai L, Wang X, Zhou L, Ceram. Int., 39, 5053 (2012)
Wang M, Yang L, Yu C, Charles C, Ceram. Int., 38, 2449 (2012)

[1] McKee DW, Fundamental Issues in Control of Carbon Gasification Reactivity, 192, 483 (1991).

[2] Manocha LM, Sadhana, 28, 349 (2003)

[3] Sogabe T, Okada O, Kuroda K, Inagaki M, Carbon, 35, 67 (1997)

[4] Fitzer G, Manocha LM, Carbon Reinforcement and Carbon/Carbon Composites, 281 (1998).

[5] Wu X, Radovic LR, Carbon, 44, 141 (2006)

[6] Isola C, Appendino P, Bosco F, Ferraris M, Salvo M, Carbon, 36, 1213 (1998)

[7] Lu W, Chung DDL, Carbon, 40, 1249 (2002)

[8] Walter S, Soraru GD, Brequel H, Enzo S, J. European Ceram. Soc., 22, 2389 (2002)

[9] Semchenko GD, Shuteeva IY, Slepchenko ON, Angolenko LA, Refractories Industrial Ceramics, 46, 260 (2005)

[10] Kowbel W, Withers JC, Ransone PO, Carbon, 33, 415 (1995)

[11] Ho CT, Chung DDL, Carbon, 28, 815 (1990)

[12] Yoo HI, Kim HS, Hong BG, Sihn IC, Lim KH, Lim BJ, Moon SY, J. European Ceram. Soc., 36, 1581 (2016)

[13] Dhami TL, Bahl OP Awasthy BR, Carbon, 33, 479 (1995)

[14] Lespade P, Richet N, Goursat P, Acta Astronaut., 60, 858 (2007)

[15] Zhu YC, Ohtani S, Sato Y, Iwamoto N, Carbon, 36, 929 (1998)

[16] Manocha LM, Manocha S, Patel KB, Glogar P, Carbon, 38, 1481 (2000)

[17] Li HJ, Xue H, Wang YJ, Fu QG, Yao DJ, Surf. Coat. Technol., 201, 9444 (2007)

[18] Paluszkiewicz C, Gumula T, Podporska J, Blazewicz M, J. Mol. Struct., 792, 176 (2006)

[19] Xia K, Lu C, Yang Y, New Carbon Materials, 30, 236 (2015)

[20] Weinmann M, Ionescu E, Riedel R, Aldinger F, Advanced Ceramics, 2, 1025 (2013)

[21] Schiavon MA, Radovanovic E, Yoshida IVP, Powder Technol., 123(2-3), 232 (2002)

[22] Kolar F, Machovic V, Svitilova J, Borecka L, Mater. Chem. Phys., 86(1), 88 (2004)

[23] Kwon OS, Hong SH, Kim H, J. European Ceram. Soc., 23, 3119 (2003)

[24] Schiavon MA, Redondo SUA, Pina SRO, Yoshida IVP, J. Non-Cryst. Solids, 304, 92 (2002)

[25] Duan L, Ma Q, Chen Z, J. European Ceram. Soc., 33, 841 (2013)

[26] Gumula T, Paluszkiewicz C, Blazewicz M, J. Mol. Struct., 704, 259 (2004)

[27] Xu T, Ma Q, Wang Y, Chen Z, Ceram. Int., 40, 13787 (2014)

[28] Li ZQ, Lu CJ, Xia ZP, Zhoh Y, Luo Z, Carbon, 45, 1686 (2007)

[29] Gumula T, Paluszkiewicz C, Blazewicz S, J. Anal. Appl. Pyrolysis, 86, 375 (2009)

[30] Wu Q, Zhang Q, Zhao L, Li SN, Wu LB, Jiang JX, Tang LC, J. Hazard. Mater., 336, 222 (2017)

[31] Guan L, Gao J, Pei Y, Zhao L, Gong L, Wan Y, Zhou Zheng N, Du X, Wu L, Jiang J, Liu H, Tang L, Mai Y, Carbon, 107, 573 (2016)

[32] Yang X, Huang Q, Su Z, Chai L, Wang X, Zhou L, Ceram. Int., 39, 5053 (2012)

[33] Wang M, Yang L, Yu C, Charles C, Ceram. Int., 38, 2449 (2012)