Journal of Industrial and Engineering Chemistry, Vol.63, 84-94, July, 2018
Simultaneous removal of NOx and soot particulates from diesel engine exhaust by 3DOM Fe.Mn oxide catalysts
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A series of three-dimensionally ordered macroporous (3DOM) Fe.Mn oxide catalysts are prepared using the colloidal crystal template method, and their catalytic performance is tested for eliminating soot and NOx. The 3DOM Fe1-Mn3-Ox catalyst exhibits the highest activity for eliminating soot and NOx. The temperature of maximum CO2 concentration (Tm) for soot combustion is 435 °C, and that for 80% NOx conversion is 302-485 °C. The high catalytic activity of 3DOM Fe1-Mn3-Ox is due to its abundant oxygen vacancies, excellent reducibility, and sufficient acid sites. The use of low-cost catalysts will be beneficial for practical applications.
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