화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.64, 478-483, August, 2018
DOI10.1016/j.jiec.2018.04.010  Export Citation
Functional group effects on a metal-organic framework catalyst for CO2 cycloaddition
Jinmi Noh, Youngik Kim, Hyojin Park, Jihyun Lee1, Minyoung Yoon1, Myung Hwan Park2, †, Youngjo Kim†, and Min Kim†
  • Department of Chemistry, Chungbuk National University, Cheongju 28644, Republic of Korea
  • 1Department of Nanochemistry, College of Bionano, Gachon University, Sungnam 13120, Republic of Korea
  • 2Department of Chemistry Education, Chungbuk National University, Cheongju 28644, Republic of Korea
E-mail:, ,
A variety of metal-organic frameworks (MOFs) have been reported as efficient catalysts for CO2 fixation reactions, such as cycloaddition to cyclic carbonates. The permanent porosity of the frameworks and theLewis acidity of the MOF metal sites have been considered as the major contributors to the catalytic activity in the cycloaddition of CO2. In this study, we have, instead, focused on the effects of the organic functional groups for effective catalytic ability. A total of eight different functionalized Zr based MOFs were tested. It was revealed that the non-functionalized pristine UiO-66 MOF (UiO = University of Oslo) showed the best conversion at low temperature (77% at 50 °C), whereas the hydroxy functionalized UiO- 66-OH MOF displayed the best conversion at high temperature (91% at 140 °C). The Zr-MOF could be recycled up to four times without a significant decrease in the reactivity.
Keywords:Metal-organic frameworks;Coordination polymers;CO2 cycloaddition;Cyclic carbonate;MOF-based catalyst
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