Perovskite-type macro/mesoporous nanotube shows large specific surface area and high utilization of catalytic sites, which gives rise to the enhancement of catalytic activity and broaden their application. In this work, perovskite-type La1-xKxFeO3-delta nanotubes were prepared for efficient soot oxidation by a simple electrospinning technique following calcination. The as-prepared samples were characterized by XRD, FI-IR, FE-SEM, TEM, XPS, N-2 adsorption-desorption, H-2-TPR and O-2-TPD techniques to investigate the physical-chemical properties. A certain amount of K+ doped in to LaFeO3-delta nanotubes sample could inhibit the growth of crystallites during the calcination at a high temperature, which could prevent the destruction of macro/mesoporous tubular structure and contribute to the more contact between soot particles and active sites. Meanwhile, it could also bring about the higher oxygen vacancy density responsible for the enhancement of redox abilities. However, excessive doping of K+ could lead to the collapsing of macro/mesoporous tubular structure, ascribable to the formation of low-melting compounds or eutectics with other components of the catalyst, which would have a negative influence on the catalytic performance. The performance for soot catalytic oxidation was evaluated in a temperature programmed oxidation device using O-2 (without or with NO) as oxidant. Among the as-prepared catalysts, the well-structured La0.8K0.2FeO3.delta nanotubes catalyst is the best candidate for soot removal.