In this work, it is studied the electrolysis with diamond anodes of three different ionic liquids (ILs): 1-butyl-3-methylimidazolium chloride (BmimCl), 1-hexyl-3-methylimidazolium chloride (HmimCl) and 1-decyl-3-methylimidazolium chloride (DmimCl), which differ only in the length of the aliphatic carbon chain attached to the imidazolium group. In addition, the effect of the presence of sulfate in the electrolyte is also evaluated. Results confirmed that this type of ILs can be completely transformed into carbon dioxide, nitrates, ammonium (the imidazolium cation) and perchlorate and chloramines (the chloride anion) during the electrolysis of the synthetic waste containing sulfate. The electrolysis of wastes without sulfate anions leads to a much less efficient process, with the same final products in the case of the BminCl and HminCl ILs and with the formation of a polymer as the main final product in the case of the DmimCl. These results are of a paramount significance from a mechanistic point of view since, because of the high conductivity of the ILs, there is not a necessity of salt addition and they inform about the pure removal of these compounds by electrolysis with BDD, pointing out the important influence of peroxodisulfate on the electrolyses with diamond of organic wastes.