Journal of Polymer Science Part A: Polymer Chemistry, Vol.34, No.17, 3495-3510, 1996
Reactivity in Radical Polymerization - Beyond the Q-E Scheme
The Q-e and Patterns of Reactivity Schemes for the quantitative treatment of the reactions of polymer radicals with monomers and transfer agents are discussed, and two revised versions of the Patterns Scheme are presented, in which all the necessary parameters are derived from experimental data on polymerizations. The new schemes provide significantly more accurate assessments of monomer reactivity ratios than do their predecessors.