The spray characteristics of hydrocarbon fuel under superheated and supercritical conditions are quite different from the traditional liquid fuel injection. In this study, the macroscopic liquid phase and vapor phase spray geometry of n-heptane was investigated by Backlit Shadowgraph and Schlieren method to investigate the differences of spray pattern under various operation conditions such as fuel temperature, injection pressure and nozzle diameter. Furthermore, both the overall and near-field spray structures were analyzed to reveal the internal mechanism. During the experiments, the ambient environment was kept constant at atmospheric condition ( 25 degrees C, 0.1 MPa), the injection pressure was varied from 3 MPa to 5 MPa, always higher than the fuel critical pressure, and the fuel temperature was changed from 25 degrees C to 300 degrees C, spanning from liquid to supercritical state. Four different spray regimes have been identified based on the fuel temperature and spray geometry: liquid regime, flash boiling regime, near-critical regime and supercritical regime. Injection paths were analyzed on the basis of thermodynamic principle. The results showed that the fuel temperature has a minor effect on the macroscopic liquid phase and vapor phase characteristics below saturated-vapor temperature of 98 degrees C at the liquid regime. As the temperature is increased to about 200 degrees C, which is in the flash boiling regime, the local spray spreading angle of both the liquid and vapor phases increases, the downstream liquid phase of spray disappears gradually and high-intensity turbulence appears in the vapor phase image. At the near-critical regime where the fuel temperature is from 200 degrees C to the critical point (267 degrees C), the local spray angle of vapor phase begins to decrease and only a small area of liquid phase at the nozzle exit can be seen, while both the shock and flash boiling are visible. When the fuel temperature goes beyond the critical point locating in supercritical regime, the fuel spray is similar to a gas jet. The steady shock structure called Mach disk was observed and the fuel temperature has little influence on the Mach disk position and diameter in the supercritical regime. However, the fuel pressure and nozzle diameter significantly affect the Mach disk position and diameter.