Advantage of high heat transfer during boiling is lost due to the absence of buoyancy induced bubble departure in space. Absence of bubble departure with pure water on an inverted heater in earth gravity (-1g) resembles boiling behavior in space and is often used to mimic zero-gravity (0g) boiling experiments on earth. Here we perform experiments on an inverted heater to show that unlike water, the aqueous solution of surface active ionic liquid (IL) avoids coalescence to form multiple small bubbles with significantly large wet area on the heater surface. The force of repulsion due to the interaction of ILs adsorbed at the liquid-vapor interface of neighboring bubbles induces a completely passive bubble departure away from the inverted heater surface against the combined effect of buoyancy and surface tension. Resulting rewetting of the heater surface increases the critical heat flux (CHF) to approximate to 950 kW/m(2), which is an enhancement of approximate to 4.5 x in comparison to pure water. Effect of bulk liquid sub cooling and concentration on pool boiling CHF are extensively investigated. The mechanism of CHF is explained with the help of the adsorption dynamics of IL at the solid-liquid and liquid-vapor interface of bubbles. (C) 2018 Elsevier Ltd. All rights reserved.