Journal of Crystal Growth, Vol.492, 77-83, 2018
TEM investigations on twin boundary structures of feathery crystals in aluminum alloys during Bridgman solidification
Feathery crystals are an ensemble of twinned dendrites, and are characterized by a unique twin boundary (TB) structure in the solidification pattern of aluminum alloys. In this work, the high-density twinned dendrites of Al-4.5 wt% Cu alloys, produced during the Bridgman solidification, have been studied using electron backscattered diffraction (EBSD) and high-resolution transmission electron microscopy (HRTEM). The experimental results showed that, after systematically decreasing the growth rate from 3000 mu m/s to 1 mu m/s, the TBs remained stable, while the solute field around the TBs changed significantly. According to the HRTEM results, successive stacking faults were occurred near the TBs at 1 mu m/s, while slight distortion was observed around the TBs at 3000 mu m/s. The composition analysis revealed an obvious solute enrichment near the TBs. Furthermore, the solute gradient profile within the TBs became smoother with the decrease in the growth speed. This is due to the more sufficient solid-state back diffusion occurring perpendicular to the twin plane after the solidification. (C) 2018 Elsevier B.V. All rights reserved.
Keywords:A1. Twinned dendrites;A1. Directional solidification;A1. Transmission electron microscopy (TEM);B1. Aluminum alloys