Microbial fuel cells (MFCs) are promising for converting biomass energy into electricity, and have attracted much research interest. However, few inexpensive high-performance anode materials for MFCs exist. In this study, MFC anodes composed of sewage sludge and different contents of fly ash (0%, 20%, 40%, 60%, and 80%) are fabricated via a one-step carbonization method. The maximum current density of 25.5 A m(-2) is achieved using the electrode with 20% fly ash, which is 37.5% higher than that of the electrode without fly ash. The improved anode performance is attributed to its good hydrophilicity, which is indicated by its water contact angle of less than 60 degrees, facile adsorption of exoelectrogens, low electron transfer resistance, and good bio-compatibility. In addition, the mechanical strength of the electrode with 20% fly ash is approximately 18 times that of the electrode without fly ash. This study reveals a promising method to fabricate high-performance MFC anodes and sheds light on the future development of MFCs using abundant municipal solid waste products.