화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.122, No.28, 7185-7190, 2018
Extraction of Radiative and Nonradiative Rate Constants of Super-Radiant J-Aggregates from Emission Spectra
Equations relating the radiative and non radiative decay rate constants of singlet excitons in super radiant aggregates to the relative intensities of the 0-0 and 0-1 peaks in the emission spectrum were derived and tested against experimental data. In many instances, these equations eliminate the need for a time-dependent fluorescence decay measurement. They can also be useful in determining the fluorescence quantum yield.