Journal of Polymer Science Part A: Polymer Chemistry, Vol.37, No.1, 69-76, 1999
New poly(amide-imide)s syntheses. XXIII. Synthesis and properties of poly(amide-imide)s derived from 4,4 '-[1,4-phenylenebis(isopropylidene-1,4-phenyleneoxy)]dianiline and various bis(trimellitimide)s
A series of poly(anmide-imide)s IIIa-m containing flexible isopropylidene and ether groups in the backbone were synthesized by the direct polycondensation of 4,4'-[1,4-phenylenebis(isopropylidene-1,4-phenyleneoxy)]dianiline (PIDA) with various bis(trimellitimide)s IIa-m in N-methyl-2-pyrrolidone (NMP) using triphenyl phosphite and pyridine as condensing agents. The resulting poly(,amide-imide)s had inherent viscosities in the range of 0.80-1.36 dL/g. Except for those from the bis(trimellitimide)s of p-phenylenediamine and benzidine, all the polymers could be cast from DMAc into transparent and tough films. They exhibited excellent solubility in polar solvents. The 10% weight loss temperatures of the polymers in air and in nitrogen were all above 495 degrees C, and their T-g values were in the range of 201-252 degrees C. Some properties of poly(amide-imide)s III were compared with those of the corresponding poly(amide-imide)s V prepared from the bis(trirmellitimide) of diamine PIDA and various aromatic diamines.
Keywords:AROMATIC POLYAMIDE-IMIDES, TRIMELLITIC ANHYDRIDE, DIRECTPOLYCONDENSATION, 4;4'-<1;4(OR 1;3)-PHENYLENEBIS(ISOPROPYLIDENE-1;4-PHENYLENEOXY)>DIANILINE;TRIPHENYL PHOSPHITE, AMINO-ACIDS, DIAMINES, 2;5-BIS(4-AMINOPHENYL)-3;4-DIPHENYLTHIOPHENE, N;N'-BIS(OMEGA-CARBOXYALKYL)PYROMELLITIMIDES, 2;7-BIS(4-AMINOPHENOXY)NAPHTHALENE