화학공학소재연구정보센터
Journal of Power Sources, Vol.385, 39-44, 2018
Porous CrN thin films by selectively etching CrCuN for symmetric supercapacitors
Transition metal nitrides are regarded as a new class of excellent electrode materials for high-performance supercapacitors due to their superior chemical stability and excellent electrical conductivity. We synthesize successfully the porous CrN thin films for binder-free supercapacitor electrodes by reactive magnetron co-sputtering and selective chemical etching. The porous CrN thin film electrodes exhibit high-capacitance performance (31.3 mF cm(-2) at 1.0 mA cm(-2)) and reasonable cycling stability (94% retention after 20000 cycles). Moreover, the specific capacitance is more than two-fold higher than that of the CrN thin film electrodes in previous work. In addition, a symmetric supercapacitor device with a maximum energy density of 14.4 mWh cm(-3) and a maximum power density of 6.6 W cm(-3) is achieved. These findings demonstrate that the porous CrN thin films will have potential applications in supercapacitors.