화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.65, 309-317, September, 2018
DOI10.1016/j.jiec.2018.04.042  Export Citation
Graphene nanosheet/polyaniline composite for transparent hole transporting layer
Olga D. Iakobson1, Oxana L. Gribkova1, Alexey R. Tameev1, 2, †, Alexander A. Nekrasov1, Danila S. Saranin3, and Aldo Di Carlo3, 4
  • 1A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Leninsky Prosp. 31, bld. 4, Moscow 119071, Russian Federation
  • 2National Research University Higher School of Economics, Myasnitskaya Str. 20, Moscow 101000, Russian Federation
  • 3National University of Science and Technology “MISiS”, Leninsky prosp. 4, Moscow 119049, Russian Federation
  • 4C.H.O.S.E. (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome “Tor Vergata”, Via del Politecnico 1, Rome 00133, Italy
E-mail:
Composites based on graphene and water-dispersible polyaniline-poly(2-acrylamido-2-methyl-1- propanesulfonic acid) complex were shown as materials promising for the development of hole transporting layers (HTLs). By using multimodal atomic force microscopy, transmission electron microscopy, cyclic voltammetry and conductivity measurements, the relationship between the oxidation degree of graphene and the morphology, electrical conductivity and electron energy structure of HTLs was revealed. Utilizing the HTLs in organic solar cells it was shown that graphene nanostacks, rather than oxidized graphene nanostacks, enhanced the performance of the cells by increasing the roughness of the HTL surface, which caused the improvement of the short circuit current.
Keywords:Graphene;Polyaniline;Surface roughness;Conductivity;Photovoltaics
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