Metallo-Supramolecular Polymers Made of Cobalt and 3,4-Propylenedioxythiophene-Bisterpyridine Complexes for Electrochromic Applications

Amol Balu Atar; Jae Yun Jeong; Namhyeon Kim; Jong S. Park

Macromolecular Research, Vol.26, No.9, 814-818, September, 2018

DOI10.1007/s13233-018-6107-z Export Citation

Metallo-Supramolecular Polymers Made of Cobalt and 3,4-Propylenedioxythiophene-Bisterpyridine Complexes for Electrochromic Applications

Amol Balu Atar, Jae Yun Jeong, Namhyeon Kim, and Jong S. Park^†

Department of Organic Material Science and Engineering, Pusan National University, Busan 46241, Korea

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In this study, a series of organometallic hybrid polymers were synthesized through the complexation of cobalt metal ions with bisterpyridine derivatives bearing substituted 3,4-propylenedioxythiophene. The prepared polymers exhibited specific color changes from orange to dark green based on the metal-to-ligand charge transfer transitions. Cyclic voltammograms of the polymers showed a reversible redox wave according to the redox reaction of the cobalt metal ions. In addition, the electrochromic devices containing the polymer film cast on an indium-tin-oxide electrode exhibited good electrochromic properties, with reversible and stable spectral transitions of the cobalt-bisterpyridine complexes.

Keywords:organometallic hybrid polymer;metallo-supramolecular polymer;electrochromic property;electrochromic device;coloration efficiency

[References]

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[Referenced By]

[1] Schlenoff JB, Laurent D, Ly H, Stepp J, Adv. Mater., 10(4), 347 (1998)

[2] Kim H, Pyo M, J. Appl. Electrochem., 30(1), 49 (2000)

[3] Choi K, Yoo SJ, Sung YE, Zentel R, Chem. Mater., 18, 5823 (2006)

[4] DeLongchamp D, Hammond PT, Adv. Mater., 13(19), 1455 (2001)

[5] Cutler CA, Bouguettaya M, Reynolds JR, Adv. Mater., 14(9), 684 (2002)

[6] (a)Delongchamp DM, Kastantin M, Hammond PT, Chem. Mater.,15, 1575 (2003). (b)Delongchamp DM, Hammond PT, Chem. Mater., 16, 4799 (2004). (c)Delongchamp DM, Hammond PT, Adv. Funct. Mater., 14, 224 (2004).

[7] (a)Decher G, Hong JD, Macromol. Symp., 46, 321 (1991). (b)Decher G, Lvov Y, Schmitt J, Thin Solid Films, 244, 772 (1994).

[8] (a)Ic-li M, Pamuk M, Algi F, Onal AM, Cihaner A, Chem. Mater., 22, 4034 (2010). (b)Suganya S, Kim N, Jeong JY, Park JS, Polymer, 116, 226 (2017).

[9] (a)Schwendeman I, Hickman R, Sonmez G, Schottland P, Zong K, Welsh D, Reynolds JR, Chem. Mater., 14, 3118 (2002). (b)Meng H, Tucker D, Chaffins S, Chen Y, Helgeson Y, Dunn B, Wudl F, Adv. Mater., 15, 146 (2003).

[10] Maier A, Rabindranath R, Tieke B, Adv. Mater., 21(9), 959 (2009)

[11] Schott M, Lorrmann H, Szczerba W, Beck M, Kurth DG, Sol. Energy Mater. Sol., 26, 68 (2014)

[12] Hsu CY, Zhang J, Sato T, Moriyama S, Higuchi M, ACS Appl. Mater. Interfaces, 7, 18266 (2015)

[13] Hsu CY, Zhang J, Moriyama S, Higuchi M, Macromol. Symp., 363, 12 (2016)

[14] Aspley CJ, Williams JAG, New J. Chem., 25, 1136 (2001)

[15] Breivogel A, Kreitner C, Heinze K, Eur. J. Inorg. Chem., 32, 5468 (2014)

[16] Chakraborty C, Rana U, Pandey RK, Moriyama S, Higuchi M, ACS Appl. Mater. Interfaces, 9, 13406 (2017)

[17] Fan CB, Ye CQ, Wang XM, Chen ZG, Zhou YY, Liang ZQ, Tao XT, Macromolecules, 48(18), 6465 (2015)

[18] Santos JJ, Toma SH, Lalli PM, Riccio MF, Eberlin MN, Tomaa HE, Araki K, Analyst, 137, 4045 (2012)

[19] Wang M, Wang K, Wang C, Huang MJ, Hao XQ, Shen MZ, Shi GQ, Zhang Z, Song B, Cisneros A, Song MP, Xu BQ, Li XP, J. Am. Chem. Soc., 138(29), 9258 (2016)

[20] Nantalaksakul A, Krishnamoorthy K, Thayumanavan S, Macromolecules, 43(1), 37 (2010)

[21] Zhao HC, Liu CY, Luo SC, Zhu B, Wang TH, Hsu HF, Yu HH, Macromolecules, 45(19), 7783 (2012)

[22] Ponder JF, Osterholm AM, Reynolds JR, Macromolecules, 49(6), 2106 (2016)

[23] Deepa M, Srivastava AK, Singh S, Agnihotry SA, J. Mater. Res., 19, 2576 (2004)

[24] Mortimer RJ, Reynolds JR, J. Mater. Chem., 15, 2226 (2005)

[25] Gaupp CL, Welsh DM, Rauh RD, Reynolds JR, Chem. Mater., 14, 3964 (2002)