화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Materials Research, Vol.28, No.9, 489-494, September, 2018
DOI10.3740/MRSK.2018.28.9.489  Export Citation
Enhanced Piezoelectric Properties of (1-x)[0.675BiFeO3.0.325BaTiO3] -xLiTaO3 Ternary System by Air-Quenching
Fazli Akram1, Rizwan Ahmed Malik1, 2, Soonil Lee1, Riffat Asim Pasha2, and Myong Ho Kim1, †
  • 1School of Materials Science and Engineering, Changwon National University, Gyeongnam 51140, Republic of Korea
  • 2Department of Metallurgy and Materials Engineering, UET Taxila, Taxila, Pakistan
E-mail:
Lead free (1-x)(0.675BiFeO3-0.325BaTiO3)- xLiTaO3 (BFBTLT, x = 0, 0.01, 0.02, and 0.03, with 0.6 mol% MnO2 and 0.4 mol% CuO) were prepared by a solid state reaction method, followed by air quenching and their crystalline phase, morphology, dielectric, ferroelectric and piezoelectric properties were explored. An X-ray diffraction study indicates that lithium (Li) and tantalum (Ta) were fully incorporated in the BFBT materials with the absence of any secondary phases. Dense ceramic samples (> 92 %) with a wide range of grain sizes from 3.70 μm to 1.82 μm were obtained in the selected compositions (0 ≤ x ≤ 0.03) of BFBTLT system. The maximum temperatures (Tmax) were mostly higher than 420 °C in the studied composition range. The maximum values of maximum polarization (Pmax ≈ 31.01 μC/cm2), remnant polarization (Prem ≈ 22.82 μC/cm2) and static piezoelectric constant (d33 ~ 145 pC/N) were obtained at BFBT-0.01LT composition with 0.6 mol% MnO2 and 0.4 mol% CuO. This study demonstrates that the high Tmax and d33 for BFBTLT ceramics are favorable for industrial applications.
Keywords:lead-free;bismuth ferrite;dielectric;ferroelectric;piezoelectric
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