Hollow carbon spheres (HCS) and carbon spheres (CS) were prepared by a hydrothermal reaction and they were introduced as a substrate for the deposition of MnO2 nanoparticles. The MnO2 nanoparticles were deposited on the carbon surface by a chemical redox deposition method. After deposition, the MnO2 nanoparticles were uniformally distributed on the carbon surface in a slit-shape, and sparse MnO2 slits appeared on the HCS surface. The MnO2-HCS showed an initial specific capacitance of 164.1 F g-1 at scan rate of 20 mv s-1, and after 1,000 cycles, the specific capacitance was maintained to 141.3 F g-1. The capacity retention of MnO2-HCS and MnO2-CS were calculated to 86% and 78% in the cycle performance test up to 1,000 cycles, respectively. MnO2-HCS showed a good cycle stability due to the mesoporous hollow structure which can cause a faster diffusion of the electrolyte and can easily adsorb and desorb Na+ ions on the surface of the electrode.