화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 168-175, October, 2018
DOI10.1016/j.jiec.2018.05.026  Export Citation
Influence of fluorinated extractant aggregation in diluent on extraction of salicylic acid: Evidence from equilibrium, SAXS and molecular dynamics simulation
Xue Wu, Zhidong Chang†, Jingge Feng, Hui Dang, Hasan Uslu1, and Wenjun Li
  • Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, PR China
  • 1Istanbul Esenyurt University, Engineering and Architecture Faculty, Industrial Engineering Department, Esenyurt, _Istanbul, Turkey
E-mail:
In order to get optimal extraction performance as well as ultra-low solvent residual, the extraction behavior of tris(2,2,3,3,4,4,4-heptafluorobutyl) phosphate (FTBP) dissolved in 2,3,4,5,6-Pentafluoroto- luene (FB) was evaluated to investigate the influence of the aggregation state on the extraction of salicylic acid (SA). The effect of SA distribution and water content on aggregation structure in organic phase was assessed through analysis of SAXS data. Based on molecular dynamic simulation, FTBP tended to aggregate with the existence of FB to accommdate more SA molcules. Water in this case was not the critical factor for aggregation formation due to the hydrophobicity of fluorinated solvents.
Keywords:Fluorinated;Solvent extraction;Aggregation;Hydrophobicity;Molecular dynamics
  1. Rao PV, Kolarik Z, Solvent Extr. Ion Exch., 14, 955 (1996)
  2. Osseo-Asare K, Metal Separation Technologies Beyond 2000: I Ntegrating Novel Chemistry with Processing, p.339 (1999).
  3. Matsumoto M, Kondo K, Hirata M, Kokubu S, Hano T, Takada T, Sep. Sci. Technol., 32(5), 983 (1997)
  4. Anitha M, Ambare DN, Singh DK, Singh H, Mohapatra PK, Chem. Eng. Res. Des., 98, 89 (2015)
  5. Maruyama T, Nakashima K, Kubota F, Goto M, Anal. Sci., 23, 763 (2007)
  6. Nakashima K, Maruyama T, Kubota F, Goto M, Anal. Sci., 25, 77 (2009)
  7. Luo Y, Chang Z, Wu X, Uslu H, Li W, Hua C, Liu S, Sun C, Im S, J. Fluor. Chem., 178, 260 (2015)
  8. Nakamura E, Hiruta Y, Watanabe T, Iwasawa N, Citterio D, Suzuki K, Anal. Sci., 31, 923 (2015)
  9. Wu X, Chang ZD, Blamo BJ, Yuan JC, Uslu H, Li WJ, Ryong CC, Fluid Phase Equilib., 449, 167 (2017)
  10. Luo Y, Chang Z, Blamo BJ, Wu X, Hussain M, Uslu H, Li W, Liu S, Sun C, Hua C, J. Fluor. Chem., 180, 234 (2015)
  11. Preston JS, Hydrometallurgy, 9, 115 (1982)
  12. Burghoff B, Schiferli J, Marques JS, de Haan AB, Chem. Eng. Sci., 64(12), 2887 (2009)
  13. Ellis RJ, Anderson TL, Antonio MR, Braatz A, Nilsson M, J. Phys. Chem. B, 117(19), 5916 (2013)
  14. Osseo-Asare K, Adv. Colloid Interface Sci., 37, 123 (1991)
  15. Pecheur O, Dourdain S, Guillaumont D, Rey J, Guilbaud P, Berthon L, Charbonnel MG, Pellet-Rostaing S, Testard F, J. Phys. Chem. B, 120(10), 2814 (2016)
  16. Osseo-Asare K, Sep. Sci. Technol., 23, 1269 (1988)
  17. Erlinger C, Gazeau D, Zemb T, Madic C, Lefrancois L, Hebrant M, Tondre C, Solvent Extr. Ion Exch., 16, 707 (1998)
  18. Ellis RJ, Meridiano Y, Muller J, Berthon L, Guilbaud P, Zorz N, Antonio MR, Demars T, Zemb T, Chem. A Eur. J., 20, 12796 (2014)
  19. Bauduin P, Testard F, Berthon L, Zemb T, Phys. Chem. Chem. Phys., 9, 3776 (2007)
  20. Jensen MP, Yaita T, Chiarizia R, Langmuir, 23(9), 4765 (2007)
  21. Qiao B, Demars T, de la Cruz MO, Ellis RJ, J. Phys. Chem Lett., 5, 1440 (2014)
  22. Wu X, Chang Z, Yuan J, Feng J, Uslu H, Li W, J. Ind. Eng. Chem. (2017).
  23. Mickelson ET, Chiang IW, Zimmerman JL, Boul PJ, Lozano J, Liu J, Smalley RE, Hauge RH, Margrave JL, J. Phys. Chem. B, 103(21), 4318 (1999)
  24. Nilsson M, Zalupski PR, Antonio MR, Ion Exchange and Solvent Extraction:Volume 21 Supramolecular Aspects of Solvent Extraction, p.197 (2013).
  25. Dejugnat C, Dourdain S, Dubois V, Berthon L, Pellet-Rostaing S, Dufreche JF, Zemb T, Phys. Chem. Chem. Phys., 16, 7339 (2014)
  26. Seduraman A, Wu P, Klahn M, J. Phys. Chem. B, 116, 296 (2011)
  27. John JV, Park H, Lee HR, Suh H, Kim I, Eur. J. Lipid Sci. Technol., 117, 1647 (2015)
  28. Yan H, Cui P, Liu CB, Yuan SL, Langmuir, 28(11), 4931 (2012)
  29. Longhi G, Fornili SL, Liveri VT, Phys. Chem. Chem. Phys., 17, 16512 (2015)
  30. Vo QN, Hawkins CA, Dang LX, Nilsson M, Nguyen HD, J. Phys. Chem. B, 119(4), 1588 (2015)
  31. Marti ME, Gurkan T, Doraiswamy LK, Ind. Eng. Chem. Res., 50(23), 13518 (2011)
  32. Essandoh M, Kunwar B, Pittman CU, Mohan D, Mlsna T, Chem. Eng. J., 265, 219 (2015)
  33. Wang X, Wei F, Qi W, Monitoring Analysis Method of Water and Wastewater, China Environmental Science Press, Beijing, China, 2002.
  34. Remde A, Debus R, Chemosphere, 32, 1563 (1996)
  35. Pan C, Ying G, Zhao J, Liu Y, Jiang Y, Zhang Q, Sci. Total Environ., 493, 580 (2014)
  36. Putnam CD, Hammel M, Hura GL, Tainer JA, Q. Rev. Biophys., 40, 191 (2007)
  37. Abraham MJ, Murtola T, Schulz R, Pall S, Smith JC, Hess B, Lindah E, SoftwareX, 1, 19 (2015)
  38. Martinez L, Andrade R, Birgin EG, Martinez JM, J. Comput. Chem., 30, 2157 (2009)
  39. Page MI, Accounts Chem. Res., 17, 144 (1984)
  40. Wang J, Wolf RM, Caldwell JW, Kollman PA, Case DA, J. Comput. Chem., 25, 1157 (2004)
  41. Darden T, York D, Pedersen L, J. Chem. Phys., 98, 10089 (1993)
  42. Essmann U, Perera L, Berkowitz ML, Darden T, Lee H, Pedersen LG, J. Chem. Phys., 103(19), 8577 (1995)
  43. Hess B, Bekker H, Berendsen HJ, Fraaije JG, J. Comput. Chem., 18, 1463 (1997)
  44. Bussi G, Donadio D, Parrinello M, J. Chem. Phys., 126, 014101 (2007)
  45. Humphrey W, Dalke A, Schulten K, J. Mol. Graph., 14, 33 (1996)
  46. Chen SH, Annu. Rev. Phys. Chem., 37, 351 (1986)
  47. Navratil JD, J. Nucl. Sci. Technol., 18, 561 (1981)
  48. Liu CQ, Cao J, Shen W, Ren YS, Mu WF, Ding XX, Fluid Phase Equilib., 408, 190 (2016)