화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 231-241, October, 2018
DOI10.1016/j.jiec.2018.05.034  Export Citation
Development of stable green emulsion liquid membrane process via liquid-liquid extraction to treat real chromium from rinse electroplating wastewater
Norul Fatiha Mohamed Noah1, Norela Jusoh1, Norasikin Othman1, 2, †, Raja Norimie Raja Sulaiman1, and Nurul Asma Mohd Khairul Parker1
  • 1Department of Chemical Engineering, Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • 2Centre of Lipids Engineering & Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research (Ibnu Sina ISIR), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
E-mail:
This research addresses the development of stable green ELM process for chromium removal from industrial effluents where CrO4 2- and Cr2O7 2- is the predominant species. Types of carriers, diluents and stripping agents undergo screening via LLE process. Meanwhile, the parameters studied for ELM stability and extraction were surfactant and modifier concentrations, homogenizer speed and emulsifying time. The formulate condition of stable ELM process was 0.04 M TOMAC in palm oil, 0.05 M NaOH, 3% (w/v) Span 80, 5% (w/v) octanol, 10,000 rpm homogenizer speed and 3 min emulsifying time. At this condition, 97% of chromium was extracted with breakage rate of 10%.
Keywords:Green solvent;Chromium;Electroplating wastewater;Droplet size distribution;Emulsion liquid membrane
  1. Othman N, Noah NFM, Poh KW, Yi OZ, Procedia Eng., 148, 765 (2016)
  2. Huang JN, Cao YH, Shao J, Peng XF, Guo ZH, Ind. Eng. Chem. Res., 56(38), 10689 (2017)
  3. Yu G, Lu Y, Guo J, Patel M, Bafana A, Wang X, Qiu B, Jeffryes C, Wei S, Guo Z, Wujcik EK, Adv. Compos. Hybrid Mater., 1, 56 (2018)
  4. Huang JH, Peng L, Zeng GM, Li X, Zhao Y, Liu LX, Li F, Chai Q, Sep. Purif. Technol., 125, 83 (2014)
  5. Huang J, Yuan F, Zeng G, Li X, Gu Y, Shi L, Liu W, Shi Y, Chemosphere, 173, 199 (2017)
  6. Fan Y, Wang X, Wang M, Hydrometallurgy, 136, 31 (2013)
  7. Sahinkaya E, Altun M, Bektas S, Komnitsas K, Miner. Eng., 32, 38 (2012)
  8. Un UT, Onpeker SE, Ozel E, J. Environ. Manage., 200, 196 (2017)
  9. Xu X, Zhang H, Lou H, Ma C, Li Y, Guo Z, Gu H, Eng. Sci., 1, 46 (2018)
  10. Maleki A, Hayati B, Naghizadeh M, Joo SW, J. Ind. Eng. Chem., 28, 211 (2015)
  11. Liu C, Fiol N, Poch J, Villaescusa I, J. Water Process Eng., 11, 143 (2016)
  12. Zhang F, Zhang YC, Zhou CQ, Yang ZJ, Xue HG, Dionysiou DD, Chem. Eng. J., 324, 140 (2017)
  13. Zhang YC, Zhang F, Yang ZJ, Xue HG, Dionysiou DD, J. Catal., 344, 692 (2016)
  14. Marinho BA, Cristovao RO, Djellabi R, Loureiro JM, Boaventura RAR, Vilar VJP, Appl. Catal. B: Environ., 203, 18 (2017)
  15. Wang CC, Du XD, Li J, Guo XX, Wang P, Zhang J, Appl. Catal. B Environ., 198 (2016).
  16. Wang M, Zhang G, Wang X, Zhang J, Rare Met, 28(3), 209 (2009)
  17. Othman N, Noah NFM, Sulaiman RNR, Abdullah NA, Bachok SK, J. Teknol. (Sci. Eng.), 68(5), 41 (2014)
  18. Noah NNFM, Othman NN, Chem. Eng. Trans., 56, 1069 (2017)
  19. Bjorkegren S, Karimi RF, Martinelli A, Jayakumar NS, Hashim MA, Membranes (Basel), 5(2), 168 (2015)
  20. Sulaiman RNR, Othman N, Saidina Amin NA, J. Ind. Eng. Chem., 20(5), 3243 (2014)
  21. Li NN, U.S. Patent 3,410,794, November 12, 1968.
  22. Jusoh N, Othman N, Malays. J. Fundam. Appl. Sci., 12(3), 114 (2016)
  23. Wang CC, Bunge AL, J. Membr. Sci., 53, 105 (1990)
  24. Li NN, Ind. Eng. Chem. Process Des. Dev., 10(2), 215 (1971)
  25. Nechifor AC, Naftanila L, Raducu A, Danciulescu V, Voicu SI, Totu EE, Recent Researches in Energy, Environment and Landscape Architecture, 10, Franta, Angers, pp.66 2011.
  26. Ahmad AL, Buddin MMHS, Ooi BS, Kusumastuti A, J. Water Process Eng., 15, 26 (2017)
  27. Chakrabarty K, Saha P, Ghoshal AK, J. Membr. Sci., 346(1), 37 (2010)
  28. Venkateswaran P, Gopalakrishnan AN, Palanivelu K, J. Environ. Sci., 19(12), 1446 (2007)
  29. Lightfoot EN, Ho WSW, Sirkar KK, Membrane Handbook, vol. 51(1992).
  30. Sulaiman RNR, Othman N, J. Hazard. Mater., 340, 77 (2017)
  31. Othman N, Noah NFM, Shu LY, Ooi ZY, Jusoh N, Idroas M, Goto M, Chin. J. Chem. Eng., 25(1), 45 (2017)
  32. Pearson G, J. Am. Chem. Soc., 85(22), 3533 (1963)
  33. Othman N, Yi OZ, Harruddin N, Malays. J. Fundam. Appl. Sci., 9(1), 41 (2013)
  34. Mane CP, Mahamuni SV, Kolekar SS, Han SH, Anuse MA, Arab. J. Chem., 9, S1420 (2016)
  35. Wionczyk B, Apostoluk W, Hydrometallurgy, 72(3-4), 185 (2004)
  36. Eyupoglu V, Kumbasar RA, J. Ind. Eng. Chem., 21, 303 (2015)
  37. Kalidhasan S, Sricharan S, Ganesh M, Rajesh N, J. Chem. Eng. Data, 55(12), 5627 (2010)
  38. Kumbasar RK, J. Ind. Eng. Chem., 16(5), 829 (2010)
  39. Garmsiri M, Mortaheb HR, Chem. Eng. J., 264, 241 (2015)
  40. Mortaheb HR, Kosuge H, Mokhtarani B, Amini MH, Banihashemi HR, J. Hazard. Mater., 165(1-3), 630 (2009)
  41. Ooi ZY, Othman N, Choo CL, J. Dispersion Sci. Technol., 37(4), 544 (2016)
  42. Othman N, Djamal R, Mili N, Zailani SN, J. Appl. Sci., 11(7) (2011)