Low cost zwitterionic adsorbent coating for treatment of anionic and cationic dyes

Syahida Farhan Azha; Muhamad Sharafee Shamsudin; Mohammad Shahadat; Suzylawati Ismail

Journal of Industrial and Engineering Chemistry, Vol.67, 187-198, November, 2018

DOI10.1016/j.jiec.2018.06.029 Export Citation

Low cost zwitterionic adsorbent coating for treatment of anionic and cationic dyes

Syahida Farhan Azha¹, Muhamad Sharafee Shamsudin¹, Mohammad Shahadat^{1, 2, †}, and Suzylawati Ismail^{1, †}

¹School of Chemical Engineering, University Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Penang, Malaysia
²Department of Biochemical Engineering & Biotechnology, Indian Institute of Technology, IIT Delhi, 110016, India

E-mail:,

Clay based coating with zwitterionic functionality is used to remove cationic and anionic dyes. Adsorbent coating was prepared by the mixing of bentonite clay, acrylic polymer (AP) and polyethylene-diamine (EPI-DMA). Characterization was performed using SEM-EDX, XRF, X-ray mapping and FTIR analyses. The adsorption capacity of ZACC was found to be increased from 59.35 to 255.99 mg/g and from 45.84 to 70.09 mg/g for BG and AR1 dyes, respectively using initial concentration (50-200 ppm). Significant adsorption capacity along with mechanical and chemical stability formulates ZACC as an excellent composite coating for treatment of anionic and cationic dyes from industrial wastewater.

Keywords:Adsorbent coating;Zwitterionic;Cationic dyes;Anionic dye;Removal capacity

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[2] Vakili M, Rafatullah M, Ibrahim MH, Abdullah AZ, Salamatinia B, Gholami Z, Carbohydr. Polym., 137, 139 (2016)

[3] Vakili M, Rafatullah M, Salamatinia B, Ibrahim MH, Abdullah AZ, Carbohydr. Polym., 132, 89 (2015)

[4] Song B, et al., Chemosphere, 172, 449 (2017)

[5] Song B, et al., Water Res., 129, 20 (2018)

[6] Jawad AH, Islam MA, Hameed BH, Int. J. Biol. Macromol., 95, 743 (2017)

[7] Azha SF, Ahmad AL, Ismail S, J. Water Process Eng., 15, 18 (2017)

[8] Kamal T, Khan S, Asiri A, Environ. Pollut., 218, 625 (2016)

[9] Azha SF, Shahadat M, Ismail S, Dyes Pigment., 145, 550 (2017)

[10] Hamid SA, Shahadat M, Ismail S, Appl. Clay Sci., 149, 79 (2017)

[11] Freni A, Frazzica A, Dawoud B, Chmielewski S, Calabrese L, Bonaccorsi L, Appl. Therm. Eng., 50(2), 1658 (2013)

[12] Dotto GL, et al., J. Environ. Chem. Eng., 4(3), 3230 (2016)

[13] Zhang W, et al., Carbohydr. Polym., 90(2), 887 (2012)

[14] Kamal T, Ul-Islam M, Khan SB, Asiri AM, Int. J. Biol. Macromol., 81, 584 (2015)

[15] Liu C, Wu P, Zhu Y, Tran L, Chemosphere, 144, 1026 (2016)

[16] Liu K, Chen L, Huang L, Lai Y, Carbohydr. Polym., 151, 1115 (2016)

[17] Espinal L, Charact. Mater., 1 (2012).

[18] Li Q, Yue QY, Su Y, Gao BY, Fu L, J. Hazard. Mater., 147(1-2), 370 (2007)

[19] Kang Q, Zhou W, Li Q, Gao B, Fan J, Shen D, Appl. Clay Sci., 45(4), 280 (2009)

[20] Li Q, Yue QY, Su Y, Gao BY, Sun HJ, Chem. Eng. J., 158(3), 489 (2010)

[21] Nosrati R, Olad A, Nofouzi K, Appl. Surf. Sci., 346, 543 (2015)

[22] Li Q, Yue QY, Sun HJ, Su Y, Gao BY, J. Environ. Manage., 91(July (7), 1601 (2010)

[23] Sharma V, Rekha P, Mohanty P, J. Mol. Liq., 222, 1091 (2016)

[24] Zhou J, Lu QF, Luo JJ, J. Clean Prod., 167, 739 (2017)

[25] Salleh MAM, Mahmoud DK, Karim WAWA, Idris A, Desalination, 280(1-3), 1 (2011)

[26] Reddy DHK, Lee SM, Adv. Colloid Interface Sci., 201-202, 68 (2013)

[27] Dutta DP, Venugopalan R, Chopade S, ChemistrySelect, 2(13), 3878 (2017)

[28] Ngulube T, Ray J, Masindi V, Maity A, J. Environ. Manage., 191, 35 (2017)

[29] Yu SJ, Wang XX, Pang HW, Zhang R, Song WC, Fu D, Hayat T, Wang XK, Chem. Eng. J., 333, 343 (2018)

[30] Yu SJ, Wang XX, Chen ZS, Wang J, Wang SH, Hayat T, Wang XK, J. Hazard. Mater., 321, 111 (2017)

[31] Song S, et al., Environ. Sci. Nano, 3(6) (2016)

[32] Li X, Liu Y, Zhang CL, Wen T, Zhuang L, Wang XX, Song G, Chen DY, Ai YJ, Hayat T, Wang XK, Chem. Eng. J., 336, 241 (2018)

[33] Zou Y, et al., J. Mater. Chem. A, 4(37), 14170 (2016)

[34] Yu S, et al., J. Mater. Chem. A, 4(15), 5654 (2016)

[35] Yu S, et al., Environ. Sci. Technol., 51(6), 3278 (2017)

[36] Wu Y, Qi H, Li B, Zhanhua H, Li W, Liu S, Carbohydr. Polym., 155, 294 (2017)

[37] Esan OS, Abiola ON, Owoyomi O, Aboluwoye CO, Osundiya MO, ISRN Phys. Chem., 2014 (2014)

[38] Nandi BK, Goswami A, Purkait MK, J. Hazard. Mater., 161(1), 387 (2009)

[39] Chieng HI, Priyantha N, Lim LBL, RSC Adv., 5(44), 34603 (2015)

[40] Laaz I, Stebe MJ, Benhamou A, Zoubir D, Blin JL, Colloids Surf. A: Physicochem. Eng. Asp., 490, 30 (2016)

[41] Mane VS, Babu PVV, Desalination, 273(2-3), 321 (2011)

[42] Huang ZH, Li YZ, Chen WJ, Shi JH, Zhang N, Wang XJ, Li Z, Gao LZ, Zhang YX, Mater. Chem. Phys., 202, 266 (2017)

[43] Wang CC, Juang LC, Lee CK, Hsu TC, Lee JF, Chao HP, J. Colloid Interface Sci., 280(1), 27 (2004)

[44] Tong DS, (Clayton) Zhou CH, Lu Y, Yu H, Zhang GF, Yu WH, Appl. Clay Sci., 50(3), 427 (2010)

[45] Akar ST, San E, Akar T, Carbohydr. Polym., 143(June), 318 (2016)