화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.67, 210-218, November, 2018
DOI10.1016/j.jiec.2018.06.031  Export Citation
EDTA-functionalized KCC-1 and KIT-6 mesoporous silicas for Nd3+ ion recovery from aqueous solutions
Seenu Ravi, Siqian Zhang, Yu-Ri Lee, Kyoung-Ku Kang1, Ji-Man Kim2, Ji-Whan Ahn3, and Wha-Seung Ahn†
  • Department of Chemical Engineering, Inha University, Incheon 402-751, Republic of Korea
  • 1Department of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 305-764, Republic of Korea
  • 2Department of Chemistry, Sungkyunkwan University, Republic of Korea
  • 3Korea Institute of Geoscience and Mineral Resource (KIGAM), 124 Gwahang-no, Daejeon 305-350, Republic of Korea
E-mail:
Ethylenediaminetetraacetic acid (EDTA)-functionalized KIT-6 and KCC-1 mesoporous silicas were prepared via post-synthesis grafting and examined for their ability to promote the recovery of rare earth metal ions such as Nd3+ from an aqueous medium. The obtained adsorption isotherms were fitted to the Langmuir model, which gave a maximum adsorption of Nd3+ ions of 109.8 and 96.5 mg/g for KIT-6-EDTA and KCC-1-EDTA, respectively, at 25 C and pH 6. The adsorption kinetic profile of KIT-6 was faster than KCC-1. KIT-6 was also proved to be more stable against desorption under acidic regeneration conditions.
Keywords:Adsorption;Rare earth elements;Mesoporous silica;KIT-6;KCC-1
  1. Moldoveanu GA, Papangelakis VG, Hydrometallurgy, 117-118, 71 (2012)
  2. Tian M, Song N, Wang D, Quan X, Jia Q, Liao W, Lin L, Hydrometallurgy, 111-112, 109 (2012)
  3. Kakoi T, Nishiyori T, Oshima T, Kubota F, Goto M, Shinkai S, Nakashio F, J. Membr. Sci., 136(1-2), 261 (1997)
  4. Sengupta A, Mohapatra PK, Patil AB, Kadam RM, Verboom W, Sep. Purif. Technol., 162, 77 (2016)
  5. Xie F, Zhang TA, Dreisinger D, Doyle F, Miner. Eng., 56, 10 (2014)
  6. Yang S, Zong P, Ren X, Wang Q, Wang X, ACS Appl. Mater. Interfaces, 4, 6891 (2012)
  7. Vojoudi H, Badiei A, Amiri A, Banaei A, Ziarani GM, Schenk-Joß K, Food Chem., 257, 189 (2018)
  8. Vojoudi H, Badiei A, Bahar S, Ziarani GM, Faridbod F, Ganjali MR, Powder Technol., 319, 271 (2017)
  9. Wang FC, Zhao JM, Pan F, Zhou HC, Yang XF, Li WS, Liu HZ, Ind. Eng. Chem. Res., 52(9), 3453 (2013)
  10. Zhao FP, Repo E, Meng Y, Wang XT, Yin DL, Sillanpaa M, J. Colloid Interface Sci., 465, 215 (2016)
  11. Yang XL, Zhang JW, Fang XH, J. Hazard. Mater., 279, 384 (2014)
  12. Anastopoulos I, Bhatnagar A, Lima EC, J. Mol. Liq., 221, 954 (2016)
  13. Yantasee W, Fryxell GE, Addleman RS, Wiacek RJ, Koonsiripaiboon V, Pattamakomsan K, Sukwarotwat V, Xu J, Raymond KN, J. Hazard. Mater., 168(2-3), 1233 (2009)
  14. Awual MR, Kobayashi T, Shiwaku H, Miyazaki Y, Motokawa R, Suzuki S, Okamoto Y, Yaita T, Chem. Eng. J., 225, 558 (2013)
  15. Schneider S, Garcez AC, Tremblay M, Bilodeau F, Lariviere D, Kleitz F, New J. Chem., 37, 3877 (2013)
  16. Zhao Y, Li J, Zhang S, Wang X, RSC Adv., 4, 32710 (2014)
  17. Zhao X, Wong M, Mao CY, Trieu TX, Zhang J, Feng PY, Bu XH, J. Am. Chem. Soc., 136(36), 12572 (2014)
  18. Luo BC, Yuan LY, Chai ZF, Shi WQ, Tang Q, J. Radioanal. Nucl. Chem., 307, 269 (2016)
  19. Huang MR, Lu HJ, Li XG, J. Mater. Chem., 22, 17685 (2012)
  20. Han C, Zhang L, Li H, Chem. Commun., 3545 (2009).
  21. Elsalamouny AR, Desouky OA, Mohamed SA, Galhoum AA, Guibal E, Int. J. Biol. Macromol., 104, 963 (2017)
  22. Galhoum AA, Mahfouz MG, Abdel-Rehem ST, Gomaa NA, Atia AA, Vincent T, Guibal E, Cellulose, 22, 2589 (2015)
  23. Li S, Chen Y, Pei X, Zhang S, Feng X, Zhou J, Wang B, Chin. J. Chem., 34, 175 (2016)
  24. Roosen J, Spooren J, Binnemans K, J. Mater. Chem. A, 2, 19415 (2014)
  25. Ravi S, Lee YR, Yu K, Ahn JW, Ahn WS, Microporous Mesoporous Mater., 258, 62 (2018)
  26. Naser AA, El-deen GES, Bhran AA, Metwally SS, El-Kamash AM, J. Ind. Eng. Chem., 32, 264 (2015)
  27. Melnyk IV, Goncharyk VP, Kozhara LI, Yurchenko GR, Matkovsky AK, Zub YL, Alonso B, Microporous Mesoporous Mater., 153, 171 (2012)
  28. Ogata T, Narita H, Tanaka M, Hydrometallurgy, 152, 178 (2015)
  29. Legaria EP, Topel SD, Kessler VG, Seisenbaeva GA, Dalton Trans., 44, 1273 (2015)
  30. Peng W, Li H, Liu Y, Song S, J. Mol. Liq., 230, 496 (2017)
  31. F. Kleitz, S. Hei Choi, R. Ryoo, Chem. Commun., 2136 (2003).
  32. Kleitz F, Berube F, Guillet-Nicolas R, Yang CM, Thommes M, J. Phys. Chem. C, 114, 9344 (2010)
  33. Fihri A, Bouhrara M, Patil U, Cha D, Saih Y, Polshettiwar V, ACS Catal., 2, 1425 (2012)
  34. Bouhrara M, Ranga C, Fihri A, Shaikh RR, Sarawade P, Emwas AH, Hedhili MN, Polshettiwar V, ACS Sustain. Chem. Eng., 1, 1192 (2013)
  35. Polshettiwar V, Cha D, Zhang X, Basset JM, Angew. Chem.-Int. Edit., 49, 9652 (2010)
  36. Sarkisov L, Monson PA, Langmuir, 17(24), 7600 (2001)
  37. Tu J, Li N, Geng W, Wang R, Lai X, Cao Y, Zhang T, Li X, Qiu S, Sens. Actuators B-Chem., 166-167, 658 (2012)
  38. Ravi S, Selvaraj M, Park H, Chun HH, Ha CS, New J. Chem., 38, 3899 (2014)
  39. Ravi S, Lee YR, Yu K, Ahn JW, Ahn WS, Microporous Mesoporous Mater., 258, 62 (2018)
  40. Kumar R, Barakat MA, Daza YA, Woodcock HL, Kuhn JN, J. Colloid Interface Sci., 408, 200 (2013)
  41. Vojoudi H, Badiei A, Amiri A, Banaei A, Ziarani GM, Schenk-Joß K, J. Phys. Chem. Solids, 113, 210 (2018)
  42. Shalini J, Sankaran KJ, Dong CL, Lee CY, Tai NH, Lin IN, Nanoscale, 5, 1159 (2013)
  43. Ravi S, Puthiaraj P, Row KH, Park DW, Ahn WS, Ind. Eng. Chem. Res., 56(36), 10174 (2017)
  44. Chen Z, Pronkin S, Fellinger TP, Kailasam K, Vile G, Albani D, Krumeich F, Leary R, Barnard J, Thomas JM, Perez-Ramirez J, Antonietti M, Dontsova D, ACS Nano, 10, 3166 (2016)
  45. Ravi S, Puthiaraj P, Ahn WS, J. CO2 Util., 21, 450 (2017)
  46. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  47. Aytas S, Yurtlu M, Donat R, J. Hazard. Mater., 172(2-3), 667 (2009)
  48. Lu Q, Ma Y, Li H, GuanX , Yusran Y, Xue M, Fang Q, Yan Y, Qiu S, Valtchev V, Angew. Chem.-Int. Edit., 57, 6042 (2018)
  49. Wu FC, Tseng RL, Huang SC, Juang RS, Chem. Eng. J., 151(1-3), 1 (2009)
  50. Ho YS, McKay G, J. Environ. Sci. Health A, 34, 1179 (1999)
  51. Sillanpaa M, Kokkonen R, Sihvonen ML, Anal. Chim. Acta, 303, 187 (1995)
  52. Kumar R, Barakat MA, Daza YA, Woodcock HL, Kuhn JN, J. Colloid Interface Sci., 408, 200 (2013)
  53. Gai SL, Li CX, Yang PP, Lin J, Chem. Rev., 114(4), 2343 (2014)