화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 87-98, December, 2018
DOI10.1016/j.jiec.2018.07.032  Export Citation
Effect of activated carbon modified with oxalic acid on the production of IPA from MX catalyzed by H3PW12O40@carbon and cobalt
Zhou-wen Fang, Hua-jie Liu, Zhi-hao Wang, Di Wen, and Xiang-li Long†
  • State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, People’s Republic of China
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The production of IPA from the oxidation of MX is completed under the catalysis of H3PW12O40 (HPW) loaded on carbon and cobalt. Oxalic acid is tried to modify the carbon to upgrade the catalytic activity of HPW@C catalyst. The experiments show that the best carbon is acquired by carbonizing the carbon at 450 °C for 2 h in N2 after being soaked in a 0.20 mol l?1 oxalic acid solution for 16 h. The IPA produced by the HPW@C catalysts prepared with the carbon modified is 58.9% over that obtained by the catalysts prepared with the original carbon.
Keywords:H3PW12O40;Oxalic acid;Activated carbon;Isophthalic acid;m-Xylene
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