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Combustion Science and Technology, Vol.190, No.11, 1886-1899, 2018
The pressure dependence of laminar flame speed of 2-methyl-2-butene/air flames in the 0.1-1.0MPa range
Laminar flame speeds of 2-methyl-2-butene/air mixtures were measured in a constant volume combustion bomb at T-0=450K, p=0.1-1.0MPa, and phi=0.5-1.6. The dependence of laminar flame speed on pressure is described by an empirical formula where the power exponent is summarized as a function of equivalence ratios (phi). The maximum at stoichiometric ratio indicates that the effect of pressure on flame is greater around the stoichiometric ratio and weaker at deviations from the stoichiometric ratio. Furthermore, analysis by chemical kinetic mechanism shows that elevated pressure is more sensitive to the reactions associated with the H and OH radicals and affects their concentration variation, and ultimately the laminar flame speed of 2-methyl-2-butene/air mixtures.