Herein, zinc cobalt layered double hydroxide (ZnCo-LDH) hybrid composites with different Zn/Co molar ratios are in-suit grown onto Ni foam by a simple and cost-effective hydrothermal approach. It is found that the Zn/Co molar ratios have an important influence on the morphology and electrochemical performance of the ZnCo-LDH composites. An interconnected nanowires structure and the highest specific capacitance were achieved when the Zn/Co molar ratio is 1: 2 (Zn1Co2-LDH).Moreover, interconnected Zn1Co2-LDH is further combined with reduced graphene oxide stuck onto Ni foam (Zn1Co2-LDH@rGO/NF) to improve its electrochemical properties. Benefiting from its unique structural feature and excellent electrical conductance ability, the as-prepared material exhibits an enhanced specific capacitance of 2142.0 F g(-1) as supercapacitor electrode. Remarkably, the assembled asymmetric supercapacitor device based on Zn1Co2-LDH@rGO/NF and active carbon delivers a high specific capacitance (149.6 F g(-1)), high energy density (53.2 Wh kg(-1)), and excellent long cycling stability (90.9% capacitance retention after 6000 cycles at 3 A g(-1)), which holds huge potential for practical application in energy conversion and storage fields. (C) 2018 Elsevier Ltd. All rights reserved.