Cool materials have been proposed for building applications given their potentialities in reducing building energy consumption, urban heat island effects, and global warming. Among cool materials, retro-reflective (RR) ones have been recently proposed for their ability to reflect backwards the incidental striking solar energy. This property is useful in densely urbanized areas, in urban canyons patterns, and in urban areas with buildings of different heights, because it avoids that the reflected energy contributes to the overheating of the neighbor buildings and structures. This study aims to predict the long-term performance of some RR tiles and paints intended for building applications. To this purpose, laboratory accelerated aging tests as described in the ASTM G154 were performed to determine the long-term material properties within a much shorter time than with outdoor weather aging. The samples show minimal changes in the reflectivity, directional reflection, and colorimetry. Finally, this paper shows that the RR character of the investigated materials and their urban cooling potential would be preserved. (C) 2018 Elsevier B.V. All rights reserved.