International Journal of Hydrogen Energy, Vol.43, No.43, 20077-20085, 2018
Modeling the performance of molten carbonate based direct carbon fuel cell anode
A mathematical model is developed to study the performance of a molten carbonate based direct carbon fuel cell anode. The direct carbon fuel cell(DCFC) is a fuel cell which uses solid carbon as fuel and molten carbonate as electrolyte. The model assumes that the 4 electron carbon oxidation reaction is the primary reaction driving the DCFC. However, the 2 electron CO oxidation reaction and the reverse Boudouard reaction is also considered in this model. The model studies the effect of performance parameters on the performance of the DCFC. The effect of the bulk conductivity in the solid phase, the bulk conductivity in the liquid phase, carbon loading and the thickness of the anode layer on the potential and current distribution in the cell is modeled. Model results are compared with experimental data and found to compare well. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.