Electrospray of Water and aqueous solutions is a simple, steady and continuous process for the production of charged droplets. Applications of this low cost spraying process, easy to scale up and environment friendly with low water consumption are first presented. This review addresses the Electro-Spray (ES) in the cone-jet mode, with focus on water ES with or without discharges in ambient air. The physical constraints to achieve steady water electrospray in ambient air are depicted to account for Electro-Hydro-Dynamic equilibrium required for the cone and jet formation on the one hand and to control electrical discharges in the gas around the liquid (with continuous corona or without any discharge) on the other hand. Operating conditions and empirical scaling laws between regulation parameters (liquid flow rate and corona current) and the properties of droplets such as the size and the charge are presented for the corona-assisted cone-jet mode of water electrospray in air. Subsequent working conditions to achieve the other steady water ES, without discharge, are then justified. The interest of this corona assisted cone-jet mode of electrospray in air for the steady production of self-dispersed unipolar water droplets (close to the Rayleigh limit) with unimodal size distribution is presented with one environmental application for filtration by bipolar-scrubbing of suspended particles from exhaust or ambient aerosols, with lab-scale efficiencies of High Efficiency Particulate Air filters.