Techno-economic evaluation of the 2,3-butanediol dehydration process using a hydroxyapatite-alumina catalyst

Daesung Song; Young-Gak Yoon; Chul-Jin Lee

Korean Journal of Chemical Engineering, Vol.35, No.12, 2348-2354, December, 2018

DOI10.1007/s11814-018-0161-2 Export Citation

Techno-economic evaluation of the 2,3-butanediol dehydration process using a hydroxyapatite-alumina catalyst

Daesung Song, Young-Gak Yoon¹, and Chul-Jin Lee^{1, †}

Department of Civil, Safety & Environmental Engineering, Hankyong National University, 327 Jungang-ro, Anseong-si, Gyeonggi-do 17579, Korea
¹School of Chemical Engineering and Materials Science, Chung-Ang University, 84 Heukseok-ro, Dongjak-gu, Seoul 06980, Korea

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We designed a conceptual model of the 2.3-BDO dehydration process using a hydroxyapatite-alumina catalyst and estimated its economic feasibility to predict the appropriate range of the purchase price of 2,3-BDO on commercial scale. The conceptual design and economic analysis can offer valuable information for the industrial application of 2,3-BDO because the most relevant studies have limitation in laboratory scale. Furthermore, the adequate range of 2,3-BDO price, in which the process has profitability, was investigated with the current market prices of 1,3-BD. The investigated price in terms of 2,3-BDO dehydration can pertain to estimation of the economic feasibility in 2,3-BDO production process.

Keywords:2,3-Butanediol Dehydration;1,3-Butadiene;Methyl Ethyl Ketone;Techno-economic Evaluation;Price of 2,3-Butanediol

[References]

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Song D, Ind. Eng. Chem. Res., 55(45), 11664 (2016)
Song D, Ind. Eng. Chem. Res., 56(39), 11013 (2017)
Song D, Catalysts, 8, 72 (2018)
Duan H, Sun D, Yamada Y, Sato S, Catal. Commun., 48, 1 (2014)
Duan HL, Yamada Y, Sato S, Appl. Catal. A: Gen., 491, 163 (2015)
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Nikitina MA, Sushkevich VL, Ivanova II, Petrol. Chem., 56, 230 (2016)
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Song D, Yoon YG, Lee CJ, Chem. Eng. Res. Des., 123, 268 (2017)
Koutinas AA, Yepez B, Kopsahelis N, Freire DMG, de Castro AM, Papanikolaou S, Kookos IK, Bioresour. Technol., 204, 55 (2016)
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[Referenced By]

[1] Cui X, Zhao X, Liu D, Green Chem., 20, 2018 (2018)

[2] Kopke M, Mihalcea C, Liew F, Tizard JH, Ali MS, Conolly JJ, Al-Sinawi B, Simpson SD, Appl. Environ. Microbiol., 77, 5467 (2011)

[3] Song D, Ind. Eng. Chem. Res., 55(45), 11664 (2016)

[4] Song D, Ind. Eng. Chem. Res., 56(39), 11013 (2017)

[5] Song D, Catalysts, 8, 72 (2018)

[6] Duan H, Sun D, Yamada Y, Sato S, Catal. Commun., 48, 1 (2014)

[7] Duan HL, Yamada Y, Sato S, Appl. Catal. A: Gen., 491, 163 (2015)

[8] Kannan SV, Pillai CN, Indian J. Chem., 7, 1164 (1969)

[9] Nikitina MA, Sushkevich VL, Ivanova II, Petrol. Chem., 56, 230 (2016)

[10] Kim H, Lee H, Park DS, Korea Patent Patent 10-2014-0167303 (2014).

[11] Kim HS, Park DR, Lee HW, Republic of Korea Patent US9511357 B2 (2015).

[12] Song D, Yoon YG, Lee CJ, Chem. Eng. Res. Des., 123, 268 (2017)

[13] Koutinas AA, Yepez B, Kopsahelis N, Freire DMG, de Castro AM, Papanikolaou S, Kookos IK, Bioresour. Technol., 204, 55 (2016)

[14] Penner D, Redepenning C, Mitsos A, Viell J, Ind. Eng. Chem. Res., 56(14), 3947 (2017)

[15] Carlson EC, Chem. Eng. Process., October, 35 (1996)

[16] Han Y, Kim H, Republic of Korea Patent 10-1298672 (2013).

[17] Han Y, Kim H, Hong J, Jho H, Korea Patent Patent 10-1287167 B1 (2013).

[18] Kim HK, Jung SY, Han C, Na BK, Chung YS, Song HK, Korean. Chem. Eng. Res., 33, 213 (1995)

[19] Greene HMLAHL, Adv. Chem., 115, 148 (1974)

[20] Lim Y, Lee CJ, Jeong YS, Song IH, Lee CJ, Han C, Ind. Eng. Chem. Res., 51(13), 4982 (2012)

[21] Turton R, Bailie RC, Whiting WB, Shaeiwitz JA, Bhattacharyya D, Analysis, synthesis, and design of chemical processes, Pearson (2013).

[22] Greiner E, Janshekar H, Kumamoto T, Zhang E, Chemical economics handbook: Methyl ethyl ketone (mek) (675.5000), IHS chemical (2015).

[23] Hyde B, Koster R, Chen W, Song A, Maselli J, Salamanca S, Global c4 olefins & elastomers: Appendix, IHS chemical (2017).

[24] Douglas JM, Conceptual design of chemical processes, Mc-Graw-Hill Chemical Engineering Series, New York (1988).