One of the great challenges in the field of photocatalysis is to develop novel photocatalysts with excellent solar-light-harvesting capacity and separation efficiency of photo-induced charge. Herein, novel CeO2/Bi2MoO6 heterojunctions were fabricated through in-situ precipitation of CeO2 nanoparticles (size: similar to 26 nm) on the surface of flower-like Bi2MoO6 superstructures (diameter: 2.1-3.5 mu m) by a simple method. The as-prepared photocatalysts were systematically characterized by a range of techniques. The photocatalytic degradation of rhodamine B (RhB) dye, methyl orange (MO) dye and tetracycline (TC) antibiotic by this novel photocatalyst was investigated under visible-light irradiation. The CeO2/Bi2MoO6 heterojunction with a CeO2/Bi2MoO6 weight ratio of 0.05 (0.05Ce-Bi) exhibited the highest photocatalytic activity with the RhB degradation efficiency of 100% in 75 min, which was considerably higher than those of pristine CeO2 (26.8%) and Bi2MoO6 (80.3%) as well as their physical mixtures (74.8%). The more efficient separation of electron-hole pairs was identified as the primary reason of the enhanced photocatalytic activity. Moreover, the synthesized material maintained satisfactory activity even after 6 recycling runs, indicating its high photocatalytic stability. Therefore, our finding offers a new avenue for development of stable and efficient heterojunction photocatalysts for environmental purification. (C) 2018 Elsevier Inc. All rights reserved.