Bio-resourced thermosetting epoxy foam was synthesized from tannic acid toward two different applications e.g., dye-decontaminating and thermo-insulating. Epoxidized tannic acid (ETA) foam was produced without using of organic volatile compounds or flammable foaming gases. The foam density, thermal conductivity and closed-cell content were studied. Besides, TGA showed high char yield (49% in N-2 and 48.3% in air) at 600 degrees C accompanied by high LOI (37.1 in N-2 and 36.8 in air). The high thermo-stability and intumescent char yield along with low thermal conductivity recommends the foam suitability for being used as an insulating material. Additionally, sorption of methylene blue onto ETA foam was kinetically investigated. The study of contact time, ionic strength, solution pH, initial sorbate concentration and desorption revealed the dependency of the sorption process to pH and initial sorbate concentration. The experimental data fitted well with the Langmuir isotherm (R-2 = 0.997), yielding maximum sorption capacity of 36.25 mg/g (ETA foam = 0.05 g, pH = 7, MB concentration = 50 ppm, Volume = 25 mL). The kinetic data verified that MB sorption could be represented by the pseudo second-order model. Overall, the ETA foam can be introduced as a candidate for removing cationic pollutants, thermal insulator, and self-extinguishing/intumescent materials.