화학공학소재연구정보센터
Journal of Membrane Science, Vol.563, 419-426, 2018
Attrition-resistant membranes for fluidized-bed membrane reactors: Double-skin membranes
Pd-Ag supported membranes have been prepared by coating a ceramic interdiffusion barrier onto a Hastelloy X (0.2 mu m media grade) porous support followed by deposition of the hydrogen selective Pd-Ag (4-5 mu m) layer by electroless plating. To one of the membranes an additional porous Al2O3-YSZ layer (protective layer with 50 wt% of YSZ) was deposited by dip-coating followed by calcination at 550 degrees C on top of the Pd-Ag layer, and this membrane is referred to as a double-skin membrane. Both membranes were integrated at the same time in a single reactor in order to assess and compare the performance of both membranes under identical conditions. The membranes have first been tested in an empty reactor with pure gases (H-2 and N-2) and afterwards in the presence of a catalyst (rhodium onto promoted alumina) fluidized in the bubbling regime. The membranes immersed in the bubbling bed were tested at 400 degrees C and 500 degrees C for 115 and 500 h, respectively. The effect of the protective layer on the permeation properties and stability of the membranes were studied. The double-skinned membraned showed a H-2 permeance of 1.55.10(-6) mol m(-2) s(-1) Pa-1 at 500 degrees C and 4 bar of pressure difference with an ideal perm-selectivity virtually infinite before incorporation of particles. This selectivity did not decay during the long term test under fluidization with catalyst particles.