Nanoemulsions (NEs) comprising ionic liquids (ILs); ethanolammonium formate (HO-EOAF), proliniumisopropylester dioctylsulfosuccinate ([ProC(3)][AOT]), and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide, ([Bmim][NTf2]) as insoluble hydrophilic, surface active, and hydrophobic components have been constructed. This novel class of colloidal formulations exhibited several contrasting properties vis-a-vis conventional water-in-oil or water in-ionic liquid or nonaqueous NEs such as (i) spontaneous formation, (ii) thermodynamic stability and isotropic nature, (iii) decrease of droplet size with increase in polar medium concentration, and (iv) high thermal and kinetic stability. Mechanisms and characteristics for such anomalies have been investigated by physical, spectroscopic, and imaging techniques. NEs have been demonstrated as versatile recyclable nanoreactors for user-friendly synthesis of materials such as metal-organic frameworks/light harvesting hybrid systems. We anticipate that this development will lead to the construction of several other need-based "all ionic-liquid nanoemulsions" in view of the flexibility provided by the tailoring nature of ILs.