Due to diverse applications of light rare earth metals (LREMs) oxides in advanced electronics and material/alloy, the recovery of pure LREMs oxides from the rare earth metals (REMs) mixture is one of the important areas of separation science. Present paper reports the systematic and selective precipitation studies to produce pure oxides of LREMs from the leach liquor of Korean monazite. Various process parameters like precipitant dose, pH of the solution, temperature and time were varied for obtaining the optimal conditions for the selective precipitation of pure LREMs from leach liquor which contains REMs and other metallic impurities. The use of 4 g/L of disodium oxalate (Na2C2O4) was found to be suitable to precipitate 98.10% of pure LREMs leaving unwanted metals in solution within 10 min when maintaining pH < 1 at room temperature. The Eh-pH diagram satisfactorily validated the obtained experimental data for LREMs recovery. The collected precipitate of LREMs as oxalate was converted to oxide at elevated temperature 400 degrees C in 3 h. Based on the experimental results, a flow sheet has been proposed for the production of pure LREMs oxide from monazite leach solution. Based on the laboratory scale proof of concept and validations, the process seems to be feasible for commercial exploitation after scale-up/pilot trials.