The molecular structure of a series of newly developed ultraviolet (UV) curable electrical contact stabilization materials, which contain polyethylene glycol (PEG)-block-polypropylene glycol (PPG)-block-polyethylene glycol (PEG) capped with methacrylate functional groups on both ends as the reactive oligomers and a methacrylated PEG as the reactive diluent was studied in detail. The effects of reactive diluents, including functionalities and compositions were investigated via a combination of dynamic mechanical analysis, differential scanning calorimetry, FT-IR spectroscopy and wide angle X-ray diffraction. All the films exhibit completely amorphous state at room temperature regardless of the composition or thermal history. However, a small amount of PPPDI molecular chains undergo crystallization upon slow cooling. This crystallization is completely inhibited when mixed with di-functional reactive diluents, owing to the high cross-link density. The introduction of mono-functional reactive diluents restricts but not completely prevents the crystallization process, which causes the resulting films to be difficult to crystallize to lower crystallinity levels. On the other hand, adding non-reactive diluents transforms the resulting films to become a fast-crystallizing material, as a result of the low cross-link density and a large portion of unreacted oligomers along with the unreactive component. Additionally, the degree of heterogeneity for the cross-linked networks is generally increased by the addition of reactive diluents. The molecular structures of PEG-b-PPG-b-PEG dimethacrylate cross-linked networks as well as mixed with different types of reactive diluents at both room temperature and crystallizing temperature were proposed. (C) 2018 Published by Elsevier Ltd.