화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.69, 269-284, January, 2019
DOI10.1016/j.jiec.2018.09.030  Export Citation
Ultrasonic assisted green synthesis of Ag:CdO nanocubes and nanospheres using Citrus limon leaves for efficient degradation of organic dyes
Minakshi Jha, Shabnam Ansari, and Navinchandra G. Shimpi†
  • Department of Chemistry, University of Mumbai, Santacruz (East), Mumbai, 400098, India
E-mail:
Ag:CdO nanocubes and nanosphere were synthesised via ultrasonic assisted green approach using Citrus limon leaves and applied for photodegradation. Nanocubes and nanosphere morphology were evident from SEM and TEM. The degradation time and apparent rate constant (from pseudo-first-order) for (2%) Ag:CdO@MB, (2%) Ag:CdO@Rh-B, (5%) Ag:CdO@MB and (5%) Ag:CdO@Rh-B system were t = 33 min (K = 0.088 min-1), t = 42 min (K = 0.032 min-1), t = 18 min (K = 0.11 min-1), t = 24 min (K = 0.0759 min-1), respectively. (5%) Ag:CdO conserve 92% of its activity after five repeated cycle. Generation of HO and O2 - radicals lead photodegradation. Photocatalytic mechanism was elucidated and degradation pattern followed pseudo-first order kinetics.
Keywords:C. limon;Ag:CdO;FEG-SEM;HRTEM;Organic dyes;Photocatalytic activity;Kinetics
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