화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.69, 324-330, January, 2019
DOI10.1016/j.jiec.2018.09.044  Export Citation
Surface modification of multi-walled carbon nanotubes to produce a new bimetallic Fe/Mn catalyst for the aerobic oxidation of hydrocarbons
Fatemeh Nejabat, and Saeed Rayati†
  • Department of Chemistry, K.N. Toosi University of Technology, P.O. Box 16315-1618, Tehran 15418, Iran
E-mail:
Fe/Mn bimetallic heterogenized catalyst [Fe/Mn(THPP)@MWCNT] was prepared by the simultaneous attachment of Mn and Fe porphyrins onto the surface of functionalized multi-walled carbon nanotubes. This new bimetallic nanohybrid displays a superior catalytic performance (81%) in comparison with their analogous monometallic counterparts (36% and 44% for Fe- and Mn-porphyrin respectively) in the oxidation of hydrocarbons with molecular oxygen as the sole oxidant. Experiments comparing bimetallic catalyst with equivalent physical mixtures of monometallic catalysts revealed the catalytic synergistic effect amongst metallic active centers onto the surface of the same nanotube, introducing a new class of bimetallic porphyrin-based catalysts for oxidation reactions.
Keywords:Multi-walled carbon nanotubes;Surface modification;Bimetallic nanohybrid;Metalloporphyrin;Aerobic oxidation;Molecular oxygen
  1. Zhang Y, Maroto-Valiente A, Rodriguez-Ramos I, Xin Q, Guerrero-Ruiz A, Catal. Today, 93, 619 (2004)
  2. Ghosh S, Acharyya SS, Tiwari R, Sarkar B, Singha RK, Pendem C, Sasaki T, Bal R, ACS Catal., 4, 2169 (2014)
  3. Zhang BW, Sheng T, Wang YX, Qu XM, Zhang JM, Zhang ZC, Liao HG, Zhu FC, Dou SX, Jiang YX, Sun SG, ACS Catal., 7, 892 (2017)
  4. Semba K, Nakao Y, J. Am. Chem. Soc., 136(21), 7567 (2014)
  5. Vu H, Goncalves F, Philippe R, Lamouroux E, Corrias M, Kihn Y, Plee D, Kalck P, Serp P, J. Catal., 240(1), 18 (2006)
  6. Wang C, Chi M, Li D, Van Der Vliet D, Wang G, Lin Q, Mitchell JF, More KL, Markovic NM, Stamenkovic VR, ACS Catal., 1, 1355 (2011)
  7. Diao W, Tengco JMM, Regalbuto JR, Monnier JR, ACS Catal., 5, 5123 (2015)
  8. Adams RD, Chen M, Elpitiya G, Potter ME, Raja R, ACS Catal., 3, 3106 (2013)
  9. SuT, Shao Q, Qin Z, Guo Z, Wu Z, ACS Catal., 8, 2253 (2018)
  10. Zhang L, Yu W, Han C, Guo J, Zhang Q, Xie H, Sun Z, Shao Q, Guo X, Hao L, Zheng Y, Guo Z, J. Electrochem. Soc., 164, 651 (2017)
  11. Zhang L, Yu W, Han C, Guo J, Zhang Q, Xie H, Shao Q, Sun Z, Guo Z, J. Electrochem. Soc., 164, 1086 (2017)
  12. Song B, Wang T, Sun H, Shao Q, Zhao J, Song K, Hao L, Wang L, Guo Z, Dalton Trans., 46, 15769 (2017)
  13. Deng W, Kang T, Liu H, Zhang J, Wang N, Lu N, Ma Y, Umar A, Guo Z, Sci. Adv. Mater., 10, 937 (2018)
  14. Du H, An Y, Wei Y, Hou L, Liu B, Liu H, Ma Y, Zhang J, Wang N, Umar A, Guo Z, Sci. Adv. Mater., 10, 1063 (2018)
  15. Sun Z, Zhang L, Dang F, Liu Y, Fei Z, Shao Q, Lin H, Guo J, Xiang L, Yerra N, Guo Z, Cryst. Eng. Comm., 19, 3288 (2017)
  16. Zhou P, Wang S, Tao C, Guo X, Hao L, Shao Q, Liu L, Wang Y, Chu W, Wang B, Luo S, Guo Z, Adv. Polym. Technol., 1 (2017).
  17. Hu Z, Shao Q, Moloney MG, Xu XR, Zhang DY, Li J, Zhang CH, Huang YD, Macromolecules, 50(4), 1422 (2017)
  18. Luo Q, Ma H, Hao F, Hou Q, Ren J, Wu L, Yao Z, Zhou Y, Wang N, Jiang K, Lin H, Guo Z, Adv. Funct. Mater., 27, 170306 (2017)
  19. Jaffar S, Nam KT, Khademhosseini A, Xing J, Langer RS, Belcher AM, Nano Lett., 4, 1421 (2004)
  20. Yang Y, Zheng Y, Cao W, Titov A, Hyvonen J, Manders JR, Xue J, Holloway PH, Qian L, Nat. Photonics, 9, 259 (2015)
  21. Li C, Zang Z, Chen W, Hu Z, Tang X, Hu W, Sun K, Liu X, Chen W, Opt. Express., 24, 15071 (2016)
  22. Han C, Li C, Zang Z, Wang M, Sun K, Tang X, Du J, Photonics Res., 5, 473 (2017)
  23. Zhang W, Shaikh AU, Tsui EY, Swager TM, Chem. Mater., 21, 3234 (2009)
  24. Maligaspe E, Sandanayaka ASD, Hasobe T, Ito O, D'Souza F, J. Am. Chem. Soc., 132(23), 8158 (2010)
  25. Yoo J, Park N, Park JH, Park JH, Kang S, Lee SM, Kim HJ, Jo H, Park J, Son SU, ACS Catal., 1 (2015).
  26. Mansuy D, Bartoli JF, Chottard JC, Lange M, Angew. Chem.-Int. Edit., 19, 909 (1980)
  27. Zhang Z, Duan Y, Zhang L, Yu M, Li J, Inorg. Chem. Commun., 58, 53 (2015)
  28. Zhou X, Ji H, J. Porphyr. Phthalocyanines, 16, 1032 (2012)
  29. Ucoski GM, Nunes FS, DeFreitas-Silva G, Idemori YM, Nakagaki S, Appl. Catal. A: Gen., 459, 121 (2013)
  30. Sun CG, Hu BC, Liu ZL, Chem. Eng. J., 232, 96 (2013)
  31. Rayati S, Nejabat F, New J. Chem., 41, 7987 (2017)
  32. Rayati S, Sheybanifard Z, Amini MM, Aliakbari A, J. Mol. Catal. A-Chem., 423, 105 (2016)
  33. Rayati S, Bohloulbandi E, Zakavi S, J. Coord. Chem., 69, 638 (2016)
  34. Rayati S, Ruzbahani SE, Nejabat F, Macroheterocycles, 10, 57 (2017)
  35. Rayati S, Sheybanifard Z, J. Iran. Chem. Soc., 13, 541 (2016)
  36. Harvey PD, Tasan S, Gros CP, Devillers CH, Richard P, Gendre PL, Bodio E, Organometallics, 34, 1218 (2015)
  37. Blusch LK, Mitevski O, Martin-Diaconescu V, Propper K, DeBeer S, Dechert S, Meyer F, Inorg. Chem., 53(15), 7876 (2014)
  38. Adler AD, Longo FR, Shergalis W, J. Am. Chem. Soc., 86, 3145 (1964)
  39. Adler AD, Longo FR, Kampas F, Kim J, J. Inorg. Nucl. Chem., 32, 2443 (1970)
  40. Balalaie S, Mahdodust M, Eshghi-Najafabadi RE, Chin. J. Chem., 26, 1141 (2008)
  41. Rayati S, Jafarzadeh P, Zakavi S, J. Inorg. Chem. Commun., 29, 40 (2013)
  42. Socrates G, Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd ed., J. Wiley and Sons, Chichester, 1995.
  43. Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK, Mater. Chem. Phys., 13, 919 (2009)
  44. Salavati-Niasari M, Bazarganipour M, Appl. Surf. Sci., 255(5), 2963 (2008)
  45. George A (ed), Biomimetic Based Applications, 2011, In-Tech; Croatia.
  46. Zhao HZ, Chang YY, Liu C, Electrochem, 17, 1657 (2013)
  47. Fu L, Lu Y, Liu Z, Zhu R, Chinese J. Catal., 37, 398 (2016)
  48. Huang G, Yuan RX, Peng Y, Chen XF, Zhao SK, Wei SJ, Guo WX, Chen X, RSC Adv., 6, 48571 (2016)
  49. Dapurkar SE, Kawanami H, Komura K, Yokoyama T, Ikushima Y, Appl. Catal. A: Gen., 346(1-2), 112 (2008)
  50. Yuan Y, Ji H, Chen Y, Han Y, Song X, She Y, Zhong R, Org. Process Res. Dev., 8, 418 (2004)
  51. Sahu S, Goldberg DP, J. Am. Chem. Soc., 138(36), 11410 (2016)
  52. Evans S, Smith JRL, J. Chem. Soc.-Perkin Trans. 2, 2, 1541 (2000)
  53. Aggarwal A, Singh S, Samson J, Drain CM, Macromol. Rapid Commun., 33(14), 1220 (2012)
  54. Mukherjee A(Ed.), Biomimetic, learning from nature, In-Tech, Croatia, 2014.
  55. Du H, Zhao ZX, Lin J, Guo J, Wang B, Hu Z, Shao Q, Pan D, Wujcik EK, Guo Z, Chem. Rec., 18, 1 (2018)
  56. Wu Z, Cui H, Chen L, Jiang D, Weng L, Ma Y, Li X, Zhang X, Liu H, Wang N, Zhang J, Ma Y, Zhang M, Huang Y, Guo Z, Compos. Sci. Technol., 164, 195 (2018)
  57. Wang YP, Zhou P, Luo SZ, Guo S, Lin J, Shao Q, Guo X, Liu Z, Shen J, Wang B, Guo Z, Adv Polym Technol. in press. https://doi.org/10.1002/adv.21969.
  58. Cui XK, Zhu GY, Pan YF, Shao Q, Zhao C, Dong MY, Zhang Y, Guo ZH, Polymer, 138, 203 (2018)
  59. Gu HB, Zhang HY, Lin J, Shao Q, Young DP, Sun LY, Shen TD, Guo ZH, Polymer, 143, 324 (2018)
  60. Wu Z, Gao S, Chen L, Jiang D, Shao Q, Zhang B, Zhai Z, Wang C, Zhao M, Ma Y, Zhang X, Weng L, Zhang M, Guo Z, Macromol. Chem. Phys., 218, 1 (2017)
  61. Hu Z, Shao Q, Huang Y, Yu L, Zhang D, Xu X, Lin J, Liu H, Guo Z, Nanotechnology, 29, 185602 (2018)
  62. Hu Z, Zhang D, Yu L, Huang Y, J. Mater. Chem. B, 6, 518 (2018)