화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.70, 116-123, February, 2019
DOI10.1016/j.jiec.2018.09.041  Export Citation
Facile electrosynthesis of Fe (Ni/Co) hydroxyphosphate as a bifunctional electrocatalyst for efficient water splitting
P.T. Babar, A.C. Lokhande, Eunae Jo, B.S. Pawar1, M.G. Gang, S.M. Pawar1, and J.H. Kim†
  • Optoelectronic Convergence Research Center, Department of Materials Science and Engineering, Chonnam National University, Gwangju 500-757, South Korea
  • 1Division of Physics and Semiconductor Science, Dongguk University, Seoul 100-715, South Korea
E-mail:
Porous iron.nickel hydroxyphosphate and iron-cobalt hydroxyphosphate electrodes are prepared by one-step electrodeposition method. The as-prepared iron.nickel hydroxyphosphate and iron-cobalt hydroxyphosphate electrodes show excellent performance for water splitting with high catalytic activity towards the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), with a lower overpotential of 220 and 235 mV for the OER and 145 and 160 mV for the HER, respectively. Moreover, two-electrode electrolyzer using iron-nickel hydroxyphosphate as both the anode and cathode requires a cell voltage of 1.65 V while iron.cobalt hydroxyphosphate requires cell voltage of 1.67 V to gain current density of 10 mA cm-2.
Keywords:Bifunctional electrocatalyst;Electrodeposition;Hydroxyphosphate;TOF
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