Corrosion inhibition of steel in 3.5% NaCl by rice straw extract

N.K. Othman; S. Yahya; M.C. Ismail

Journal of Industrial and Engineering Chemistry, Vol.70, 299-310, February, 2019

DOI10.1016/j.jiec.2018.10.030 Export Citation

Corrosion inhibition of steel in 3.5% NaCl by rice straw extract

N.K. Othman¹, S. Yahya^{1, 2, †}, and M.C. Ismail²

¹School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia
²Department of Mechanical Engineering, Centre for Corrosion Research, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak, Malaysia

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Inhibition of steel corrosion in 3.5% sodium chloride (NaCl) by rice straw extract (RSE) was studied via weight loss method up to 42 days immersion. The corrosion inhibition efficiency (IE) showed a consistent value with the highest IE of 92% and low corrosion rate, 0.013 mm/y. RSE was able to reduce pitting corrosion by presenting small hysteresis loop via cyclic polarization measurement. The formation of ferric-RSE layer due to complexation was confirmed via surface analysis. The presence of corrosion products on steel was significantly reduced by immersion in RSE. The inhibitory mechanism was proposed to be achieved through interphase inhibition.

Keywords:Corrosion inhibitor;Plant extract;Steel;Weight loss;Interphase inhibition

[References]

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[Referenced By]

[1] Moller H, Boshoff ET, Froneman H, J. South African Inst Min. Metall., 106, 585 (2006)

[2] Rahim AA, Kassim J, Recent Patents Mater. Sci., 1(3), 223 (2008)

[3] Lorenz WJ, Mansfeld F, Electrochim. Acta, 31(4), 467 (1986)

[4] Sun R, BioResources, 4, 452 (2008)

[5] Akbarzadeh E, Ibrahim MNM, Rahim AA, Int. J. Electrochem. Sci., 6, 5396 (2011)

[6] Vagin MY, Trashin SA, Karyakin AA, Electrochem. Commun., 8, 60 (2006)

[7] Altwaiq A, Khouri J, Al-luaibi S, Lehmann R, Drucker H, Vogt C, J. Mater. Environ. Sci., 2(3), 259 (2011)

[8] Ren Y, Luo Y, Zhang K, Zhu G, Tan X, Corrosion Sci., 50(11), 3147 (2008)

[9] Verma C, Ebenso EE, Quraishi MA, J. Mol. Liq., 248, 927 (2017)

[10] Xhanari K, Finsgar M, Arab. J. Chem. (2016) In press, corrected proof, https://doi.org/10.1016/j.arabjc.2016.08.009.

[11] Dong L, Yuanhua L, Yigang D, Dezhi Z, Anti-Corrosion Methods Mater., 58(4), 205 (2011)

[12] Zulkafli R, Othman NK, Jalar A, AIP Conf. Proc., 48, 48 (2013)

[13] Mahross M, Naggar A, Seaf Elnasr T, Abdel-Hakim M, Chem. Adv. Mater., 6(16), 6 (2016)

[14] Yahya S, Othman NK, Daud AR, Jalar A, Sains Malaysiana, 42(12), 1793 (2013)

[15] ASTMG1-03, Standard Practice for Preparing, Cleaning and Evaluation Corrosion Test Specimens, (1999).

[16] Belanger H, Pat. Appl. Publ. US 2009/00(8) (2009).

[17] Sun R, Lawther JM, Banks WB, Ind. Crop. Prod., 6(1), 1 (1997)

[18] ASTM G 31-72, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, vol 72(2004).

[19] Sastri VS, Ghali E, Elboujdaini M, Corrosion Prevention Protection Practical Solutions, JohnWiley & Ltd. Sons, West Sussex England, 2007.

[20] Sastri VS, Perumareddi JR, Corrosion, 9312 (1994).

[21] Nordsveen M, Nes S, Corrosion, 59(5), 443 (2003)

[22] Eliyan FF, Alfantazi A, Corrosion, 9312, 880 (2014)

[23] Rahim A, Rocca E, Steinmetz J, Jain Kassim M, Corrosion Sci., 50(6), 1546 (2008)

[24] Al Juhaiman LA, Mustafa AA, Mekhamer WK, Anti-Corrosion Methods Mater., 60(1), 28 (2013)

[25] Hamdy A, El-Gendy NS, Egypt. J. Pet., 22(1), 17 (2013)

[26] Nasrazadani S, Corrosion Sci., 39, 1845 (1997)

[27] Collazo A, Novoa XR, Perez C, Puga B, Electrochim. Acta, 53(25), 7565 (2008)

[28] Sparks DL, Chen C, Functions of Natural Organic Matter in Changing Environment, p.7 2013.

[29] Hu J, Cao S, Xie J, Anti-Corrosion Methods Mater., 60(2), 100 (2013)

[30] Abbasov VM, Abd El-Lateef HM, Aliyeva LI, Qasimov EE, Ismayilov IT, Khalaf MM, Egypt. J. Pet., 22(4), 451 (2013)

[31] Islam MA, Farhat ZN, Ahmed EM, Alfantazi A, Wear, 302(1-2), 1592 (2013)

[32] Amin MA, Mohsen Q, Mersal GAM, Port. Electrochim. Acta, 28(2), 95 (2010)

[33] Trdan U, Grum J, Corrosion Sci., 59, 324 (2012)

[34] Poursaee A, Electrochim. Acta, 55(3), 1200 (2010)

[35] Amin, Corrosion Sci., 52(10), 3243 (2010)

[36] Finsgar M, Fassbender S, Nicolini F, Milosev I, Corrosion Sci., 51(3), 525 (2009)

[37] Almeida E, Pereira D, Figueiredo MO, Lobo VMM, Morcillo M, Corrosion Sci., 39(9), 1561 (1997)