화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.70, 330-337, February, 2019
DOI10.1016/j.jiec.2018.10.033  Export Citation
Synthesis of the crystalline porous copper oxide architectures derived from metal-organic framework for electrocatalytic oxidation and sensitive detection of glucose
Lili Li1, 2, Yaoyao Liu1, Lunhong Ai1, †, and Jing Jiang1, †
  • 1Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637002, PR China
  • 2i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences (CAS), 398 Ruoshui Road, Suzhou 215123, PR China
E-mail:,
The porous CuO architectures have been successfully synthesize by the effective transformation of a Cu-BTC metal-organic frameworks (MOFs) through a facile heating treatment. The as-synthesized porous CuO architectures exhibit high electrocatalytic activity toward the glucose oxidation. When evaluated as a nonenzymatic glucose biosensor, the porous CuO architectures manifest fast response within 1.3 s, wide linear range from 0.5 mM to 2.8 μM, low detection limit of 0.1 μM (signal-to-noise ratio of 3), high sensitivity up to 934.2 μA mM-1cm-2 as well as favorable reproducibility.
Keywords:CuO;Chemical transformation;Nonenzymatic biosensor;Glucose
  1. Mitro N, Mak P, Vargas L, Godio C, Hampton E, Molteni V, Kresuch A, Saez E, Nature, 445, 219 (2007)
  2. Cao X, Wang N, Jia S, Shao Y, Anal. Chem., 85, 5040 (2013)
  3. Heller A, Feldman B, Chem. Rev., 108(7), 2482 (2008)
  4. Kimmel DW, LeBlanc G, Meschievitz ME, Cliffel DE, Anal. Chem., 84, 685 (2012)
  5. Chen C, Xie Q, Yang D, Xiao H, Fu Y, Tan Y, Yao S, RSC Adv., 3, 4473 (2013)
  6. Tian K, Prestgard M, Tiwari A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 41, 100 (2014)
  7. Zhu X, Ju Y, Chen J, Liu D, Liu H, ACS Sens., 3, 1135 (2018)
  8. Dong Q, Huang Y, Song D, Wu H, Cao F, Lei Y, Biosens. Bioelectron., 112, 136 (2018)
  9. Wang X, Ge CY, Chen K, Zhang YX, Electrochim. Acta, 259, 225 (2018)
  10. Manjakkal L, Sakthivel B, Gopalakrishnan N, Dahiya R, Sens. Actuators B-Chem., 263, 50 (2018)
  11. Gou X, Sun S, Yang Q, Li P, Liang S, Zhang X, Yang Z, New J. Chem., 42, 6364 (2018)
  12. Reitz E, Jia W, Gentile M, Wang Y, Lei Y, Electroanalysis, 20, 2482 (2008)
  13. Zhang Y, Liu Y, Su L, Zhang Z, Huo D, Hou C, Lei Y, Sens. Actuators B-Chem., 191, 86 (2014)
  14. Wang W, Zhang L, Tong S, Li X, Song W, Biosens. Bioelectron., 25, 708 (2009)
  15. Liu S, Tian J, Wang L, Qin X, Zhang Y, Luo Y, Asiri AM, Al-Youbicd AO, Sun X, Catal. Sci. Technol., 2, 813 (2012)
  16. Wang J, Zhang WD, Electrochim. Acta, 56(22), 7510 (2011)
  17. Sun S, Zhang X, Sun Y, Zhang J, Yang S, Song X, Yang Z, RSC Adv., 3, 13712 (2013)
  18. Amani-Beni Z, Nezamzadeh-Ejhieh A, J. Colloid Interface Sci., 504, 186 (2017)
  19. Zhang X, Sun S, Lv J, Tang L, Kong C, Song X, Yang Z, J. Mater. Chem. A, 2, 10073 (2014)
  20. Bae JH, Han JH, Chung TD, Phys. Chem. Chem. Phys., 14, 448 (2012)
  21. Park S, Kim HC, Chung TD, Analyst, 137, 3891 (2012)
  22. Menshykau D, Compton RG, Electroanalysis, 20, 2387 (2008)
  23. Lee KJ, Lee JH, Jeoung S, Moon HR, Accounts Chem. Res., 50, 2684 (2017)
  24. Guan BY, Yu XY, Wu HB, Lou XW, Adv. Mater., 29, 201703 (2017)
  25. Zou KY, Li ZX, Chem. Eur. J., 24, 6506 (2018)
  26. Tang J, Yamauchi Y, Nat. Chem., 8, 638 (2016)
  27. Cao X, Tan C, Sindoro M, Zhang H, Chem. Soc. Rev., 46, 2660 (2017)
  28. Dang S, Zhu L, Xu Q, Nat. Rev. Mater., 3, 17075 (2017)
  29. Zhang C, Ai L, Jiang J, J. Mater. Chem. A, 3, 3074 (2015)
  30. Salunkhe RR, Kaneti YV, Yamauchi Y, ACS Nano, 11, 5293 (2017)
  31. Abney CW, Patterson JT, Gilhula JC, Wang L, Hensley DK, Chen J, Foo GS, Wu Z, Dai S, J. Mater. Chem. A, 5, 13565 (2017)
  32. Guo W, Sun W, Lv LP, Kong S, Wang Y, ACS Nano, 11, 4198 (2017)
  33. Young C, Wang J, Kim J, Sugahara Y, Henzie J, Yamauchi Y, Chem. Mater., 30, 3379 (2018)
  34. Zhao SN, Song XZ, Song SY, Zhang HJ, Coord. Chem. Rev., 337, 80 (2017)
  35. Li X, Zeng C, Jiang J, Ai L, J. Mater. Chem. A, 4, 7476 (2016)
  36. Wei C, Li X, Xu F, Tan H, Li Z, Sun L, Song Y, Anal. Methods, 6, 1550 (2014)
  37. Gai P, Zhang H, Zhang Y, Liu W, Zhu G, Zhang X, Chen J, J. Mater. Chem. B, 1, 2742 (2013)
  38. Hou C, Xu Q, Yin L, Hu X, Analyst, 137, 5803 (2012)
  39. Mai HD, Sung GY, Yoo H, RSC Adv., 5, 78807 (2015)
  40. Song YH, He J, Wu HL, Li X, Yu J, Zhang YY, Wang L, Electrochim. Acta, 182, 165 (2015)
  41. Ai L, Li L, Zhang C, Fu J, Jiang J, Chem. Eur. J., 19, 15105 (2013)
  42. DeCoste JB, Peterson GW, Schindler BJ, Killops KL, Browe MA, Mahle JJ, J. Mater. Chem. A, 1, 11922 (2013)
  43. Szanyi J, Daturi M, Clet G, Baerc DR, Pedena CHF, Phys. Chem. Chem. Phys., 14, 4383 (2012)
  44. Kong C, Tang L, Zhang X, Sun S, Yang S, Song X, Yang Z, J. Mater. Chem. A, 2, 7306 (2014)
  45. Wang J, Liu YC, Wang SY, Guo XT, Liu YP, J. Mater. Chem. A, 2, 1224 (2014)
  46. Kang X, Mai Z, Zou X, Cai P, Mo J, Anal. Biochem., 363, 143 (2007)
  47. Song J, Xu L, Zhou C, Xing R, Dai Q, Liu D, Song H, ACS Appl. Mater. Interfaces, 24, 12928 (2013)
  48. Yuan RM, Li HJ, Yin XM, Lu JH, Zhang LI, Talanta, 174, 514 (2017)
  49. Gao Z, Liu J, Chang J, Wu D, He J, Wang K, Xu F, Jiang K, CrystEngComm, 14, 6639 (2012)
  50. Maji SK, Dutta AK, Bhadu GR, Paul P, Mondal A, Adhikary B, J. Mater. Chem. B, 1, 4127 (2013)
  51. Zhao J, Wei L, Peng C, Su Y, Yang Z, Zhang L, Wei H, Zhang Y, Biosens. Bioelectron., 47, 86 (2013)
  52. Liu S, Yu B, Zhang T, Electrochim. Acta, 102, 104 (2013)
  53. Ding Y, Wang Y, Su L, Bellagamba M, Zhang H, Lei Y, Biosens. Bioelectron., 26, 542 (2010)
  54. Hou C, Xu Q, Yin L, Hu X, Analyst, 137, 5803 (2012)
  55. Leonardi SG, Marini S, Espro C, Bonavita A, Galvagno S, Neri G, Microchimica. Acta, 184, 2375 (2017)
  56. Zhu W, Wang J, Zhang W, Hu N, Huang L, Wang R, Suo Y, Wang J, J. Mater. Chem. B, 6, 718 (2018)
  57. Wu M, Meng S, Wang Q, Si W, Huang W, Dong X, ACS Appl. Mater. Interfaces, 7, 21089 (2015)
  58. Wei ZY, Zhu WX, Li YG, Ma YY, Wang J, Hu N, Suo YR, Wang JL, Inorg. Chem., 57(14), 8422 (2018)