Rapid removal of methyl orange by a UV Fenton-like reaction using magnetically recyclable Fe-oxalate complex prepared with rice husk

Jun Neoung Heo; Jeong Yeon Do; Namgyu Son; Junyeong Kim; Yang Soo Kim; Haejin Hwang; Misook Kang

Journal of Industrial and Engineering Chemistry, Vol.70, 372-379, February, 2019

DOI10.1016/j.jiec.2018.10.038 Export Citation

Rapid removal of methyl orange by a UV Fenton-like reaction using magnetically recyclable Fe-oxalate complex prepared with rice husk

Jun Neoung Heo, Jeong Yeon Do^†, Namgyu Son, Junyeong Kim, Yang Soo Kim¹, Haejin Hwang², and Misook Kang^†

Department of Chemistry, College of Natural Sciences, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Republic of Korea
¹Jeonju Center, Korea Basic Science Institute, Jeonju-si, Jeollabuk-do, 54907, Republic of Korea
²Department of Materials Science and Engineering, Inha University, Incheon 22212, Republic of Korea

E-mail:,

Porous Fe-oxalate complexes were prepared by thermally treating iron sources and rice husks under nitrogen gas purging. Fe oxidation states of 0, 2.5+, and 3+ in the complex were identified by X-ray photoelectron spectroscopy, which were oxidized into ferrites and separated by the magnet after removal of methyl orange. The Fe-oxalate complex treated at 700 C exhibited the strongest magnetic properties, and its catalytic ability to remove 100 ppm of methyl orange was optimized after 60 min. In conclusion, the oxalate ions in Fe-oxalate complex could promote the decomposition of organic compounds accelerating the OH radical generation in a UV Fenton-like system.

Keywords:Fe-oxalate complex;Rise husk;UV Fenton-like system;Methyl orange destruction;Recyclable catalyst

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[Referenced By]

[1] Barros AL, Pizzolato TM, Carissimi E, Schneider IAH, Miner. Eng., 19(1), 87 (2006)

[2] Lucas MS, Peres JA, Dyes Pigment., 71, 236 (2006)

[3] Kang SF, Liao CH, Chen MC, Chemosphere, 46, 923 (2002)

[4] Kim TH, Park C, Yang JM, Kim S, J. Hazard. Mater., 112(1-2), 95 (2004)

[5] Azbar N, Yonar T, Kestioglu K, Chemosphere, 55, 35 (2004)

[6] Ebrahiem EE, Al-Maghrabi MN, Mobarki AR, Arabian J. Chem., 10, 1674 (2017)

[7] Gadhi TA, Hernandez S, Castellino M, Chiodoni A, Husak T, Barrera G, Allia P, Russo N, Tagliaferro A, J. Ind. Eng. Chem., 63, 437 (2018)

[8] Zhang JJ, Qi P, Li J, Zheng X, Liu P, Guan XX, Zhen GP, J. Ind. Eng. Chem., 61, 407 (2018)

[9] Phan TTN, Nikoloski AN, Bahri PA, Li D, J. Ind. Eng. Chem., 61, 53 (2018)

[10] Bastami TR, Ahmadpour A, Hekmatikar FA, J. Ind. Eng. Chem., 51, 244 (2017)

[11] Nansheng D, Feng W, Fan L, Mei X, Chemosphere, 36, 3101 (1998)

[12] Wang Z, Chen C, Ma W, Zhao J, J. Phys. Chem. Lett., 3, 2044 (2012)

[13] Baker AD, Casadavell A, Gafney HD, Gellender M, J. Chem. Eng., 57, 314 (1980)

[14] Feng X, Ding S, Xie F, Bull. Korean Chem. Soc., 33, 3686 (2012)

[15] Amiri AS, Bolton JR, Cater SR, Solar Energy, 56, 439 (1996)

[16] Zhou T, Wu XH, Mao J, Zhang YR, Lim TT, Appl. Catal. B: Environ., 160, 325 (2014)

[17] Li F, Chen J, Liu C, Dong J, Liu T, Biol. Fertil. Soils, 42, 409 (2006)

[18] Rodriguez M, vis based advanced oxidation processes in wastewater treatment, 2003.

[19] Dai H, Xu S, Chen J, Miao X, Zhu J, Chemosphere, 199, 147 (2018)

[20] Chen JX, Zhu LZ, J. Hazard. Mater., 185(2-3), 1477 (2011)

[21] Kim Y, Lee J, Jeong H, Lee Y, Um MH, Jeong KM, Yeo MK, Kang M, J. Ind. Eng. Chem., 14(3), 396 (2008)

[22] Chen JX, Zhu LH, Catal. Today, 126(3-4), 463 (2007)

[23] Hu Z, Deng Y, Li K, Yang S, Nanoscale Res. Lett., 7, 1 (2012)

[24] Viertelhaus M, Adler P, Cle’rac R, Anson CE, Powell AK, Eur. J. Inorg. Chem. 692 (2005).

[25] Rousse G, Rodriguez-Carvajald J, Dalton Trans., 45, 14311 (2016)

[26] Bateer B, Tian C, Qu Y, Du S, Tan T, Wang R, Tian G, Fu H, Cryst. Eng. Comm., 15, 3366 (2013)

[27] Luo M, Olivier GK, Frechette J, Soft Mater, 8, 11923 (2012)

[28] Parekh BB, Vyas PM, Vasant SR, Joshi MJ, Bull. Thermal Mater. Sci., 31, 143 (2008)

[29] Porter JF, Li YG, Chan CK, J. Mater. Sci., 34(7), 1523 (1999)

[30] Liu G, Zheng S, Xing X, Li Y, Yin D, Ding Y, Pang W, Chemosphere, 78, 402 (2010)

[31] Su Z, Zhang Y, Liu B, Chen Y, Li G, Jiang T, Sci. Rep., 7, 1 (2017)

[32] Sagar E, Shirsath X, Liu Y, Yasukawa S, Li S, Morisako S, Sci. Rep., 6, 1 (2016)

[33] Desimoni E, Brunetti B, Chemosensors, 3, 70 (2015)

[34] Chagas P, da Silva AC, Passamani EC, Ardisson JD, de Oliveira LCA, Fabris JD, Paniago RM, Monteiro DS, Pereira MC, J. Nanopart. Res., 15, 1 (2013)