화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.70, 427-438, February, 2019
DOI10.1016/j.jiec.2018.11.005  Export Citation
Characterization and properties of new color-tunable hybrid pigments based on layered double hydroxides (LDH) and 1,2-dihydroxyanthraquinone dye
Anna Marzec†, Boleslaw Szadkowski, Jacek Rogowski1, Waldemar Maniukiewicz1, Marcin Kozanecki2, Dariusz Moszynski3, and Marian Zaborski
  • Institute of Polymer and Dye Technology, Lodz University of Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland
  • 1Institute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
  • 2Department of Molecular Physics, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
  • 3Institute of Inorganic Chemical Technology and Environment Engineering, West Pomeranian University of Technology, Pułaskiego 10, 70-322 Szczecin, Poland
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In this paper a novel, simple method for synthesis of lake pigments based on 1,2-dihydroxyanthra- quinone dye and LDH carbonates was proposed. LDHs were modified with 1,2-dihydroxyanthraquinone, transforming the soluble dye into a new kind of hybrid lake. In result, the solvent resistance and photostability of the chromophore were improved, which may be attributed to strong dye-LDH interactions. TOF-SIMS technique was used for the first time to confirm the role of C14H7O4Mg+ and C14H6O5Al- ions in the formation of the hybrids. Alizarin lakes have been recognized as a new class of colorants which demonstrated good color characteristics and chemical stability.
Keywords:Color-tunable pigment;1,2-Dihydroxynaphtoquinone;Layered double hydroxide;Organic.inorganic hybrids;TOF-SIMS
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