Hierarchical nanostructures of bismuth sulfide (Bi2S3) have been synthesized by a facile hydrothermal method. The potentiality of Bi2S3 hierarchical nanostructures for the photocatalytic degradation of Rhodamine B (RhB), Methylene blue (MB) and the mixture of RhB-MB organic dyes have been demonstrated and compared with commercial TiO2 (Degussa P25) sample under visible light illumination. The degradation efficiency of Bi2S3 and Degussa P25 is found to be higher in the single as well as in the binary dye solution for MB degradation as compared to RhB degradation. Furthermore, the degradation rate of RhB and MB is enhanced by similar to 8 times and similar to 3 times in their binary solution as compared to that in single dye solution. Whereas, Bi2S3 has demonstrated similar to 14 times higher degradation rate of both RhB and MB in their binary solution than that of Degussa P25 for RhB and MB degradation in the binary solution under visible light exposure, respectively. Interestingly, Bi2S3 nanostructures has exhibited larger improvement in the degradation efficiency for RhB in its binary solution which is attributed to the faster separation of photogenerated charge carriers due to the proper alignments between the molecular orbits of dyes and band level positions of Bi2S3 in RhB-MB-Bi2S3 heterogenous system. The photocatalytic degradation study of colourless contaminants, p-chlorophenol (CP), p-nitrophenol (NP) and their mixture (CP-NP) is also investigated in the presence of Bi2S3 nanoflowers. Among the phenolic compounds, the degradation rate of NP is observed to be highest in the single solution. However, the degradation rate of both CP and NP is found to decrease in binary mixture solution in comparison to their individual solution. A possible mechanism for the enhanced photodegradation of RhB-MB dye mixture based on the active species trapping experiment has been proposed. (C) 2018 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.