In this work, heterostructured Au@PbTiO3 nanoplates were synthesized successfully via a simple hydrothermal process. It is revealed that Au islands with the size of 8-20 nm selectively deposited on the positively polarized surface of the single-crystal and single-domain PbTiO3 nonaplates. The composite demonstrates an efficient photocatalytic performance toward degradation of Rhodamine B (RhB) solution under UV light The possible mechanism is that the ferroelectric polarization efficiently separates the photogenerated electrons and holes and reduces the recombination of them. Then, the ferroelectric polarization field urged the electrons concentrated on the positively polarized surface and then transformed oxygen into superoxide radicals to enhance the photocatalytic activity. Recycled activity tests show that the heterostructured Au@PbTiO3 nanoplates would inhibit the photocorrosion behavior and provide high stability.