Stannous oxide (SnO) and stannic oxide (SnO2) are both important wide-band-gap semiconductors. To study the conducive mechanism in detail, high quality epitaxial films are essential. Here we propose a simple method to grow high quality epitaxial films of either stannous oxide or stannic oxide on an r-plane sapphire substrate by using pulsed laser deposition with a metallic tin target. The valence state of tin is controlled by tuning the oxygen pressure during the deposition procedure. Metal tin impurities and the transition phase of Sn3O4 are avoided and the growth windows from stannous oxide to stannic oxide are confirmed. For single-crystalline SnO epitaxial film, a rocking curve half-width of 0.22 degrees is obtained, which is better than the 0.46 degrees of that on a YSZ substrate. The minimum roughnesses achieved were 0.37 nm for the SnO2 epitaxial film and 0.84 nm for the SnO epitaxial film. The epitaxial relationship between SnO and the r-sapphire substrate was determined to be SnO [(1) over bar 1 0]//sapphire [(1) over bar 2 (1) over bar 0] and SnO [1 1 0]//sapphire [1 0 (1) over bar 1]. For SnO2, the epitaxial relation is SnO2 [0 1 0]//sapphire [(1) over bar 2 (1) over bar1 0] and SnO2 [(1) over bar 0 1]//sapphire [1 0 (1) over bar 1]. The band schematics, deduced by combined XPS valence band spectroscopy and optical transmittance spectroscopy, indicated p-type bands of SnO and n-type bands of SnO2. Raman spectroscopy is suggested to be a superior fingerprint of SnO single-crystalline quality, due to its greater sensitivity than X-ray diffraction.