The nanostructuring of materials can solve the problem of low conductivity of the vanadate electrode, thereby increasing the potential for lithium storage performance. The traditional battery is prepared by coating active materials on current collector, which produces large contact resistance between the current collector and the electrodes, impeding the overall electrochemical performances of the battery. In this work, we propose and verify a scheme for directly loading porous iron vanadate nanowire array electrode on titanium foil. The resultant electrode (the as-prepared iron vanadate annealed at 300 degrees C) exhibits an enhanced lithium storage performance, the discharge capacity after 100 cycles is 1041.10 mAh.g(-1) at a current density of 300 mA.g(-1). The iron vanadate nanowire electrode is fabricated by a simple and scalable cation-exchange method, which can be provided for the separate and integrated large-scale industrialization of vanadate electrode materials.